Conventional and rapid thermal annealing of spray pyrolyzed copper indium gallium sulfide thin films
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Keywords:
Spray pyrolysis
Copper sulfide
Gallium Oxide
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Spray pyrolysis
Copper sulfide
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Abstract Die Titelsysteme sind quasibinär und enthalten jeweils eine intermediäre inkongruent schmelzende Verbindung der Zusammensetzung (Ga,In)SX.
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Dithiocarbamate
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Heterobimetallic Group 11/13 sulfide nanoparticles (AgInS2 , CuInS2 , Ag9 GaS6 , and CuGaS2 ) are formed by treatment of [M(S2 CAr)3 ] (M=Ga or In) with either AgNO3 or CuCl under mild conditions. The intermediary gallium or indium tris(aryldithioate) complexes are easily prepared by stirring the appropriate metal and aryldithioc acid at room temperature. Overall, this two-step process is a simple solution-based method for transforming Ga and In metal into valuable ternary metallosulfide nanoparticles at relatively low temperatures.
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An counterpart-shaped gallium-sulfide molecular ring with its indium alloyed one toward efficient photocatalytic dye degradation and comparable photocatalytic hydrogen production.
Degradation
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Dip-coating
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Abstract Liquidus‐Messungen im Cu,In,S‐System entlang dem pseudobinären Cumslnms‐Szeigen einen Schmelzpunkt von 1 l 15°C für CuInSQ.
Liquidus
Copper sulfide
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Nanosecond
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Abstract Indium and gallium indium sulfide thin films were deposited on soda‐lime glass substrates at 350 °C, in a wide range of sulfur delivery conditions, by Modulated Flux Deposition (MFD). Indium sulfide films were highly crystalline β‐In 2 S 3 (tetragonal) with E g = 2.68 eV. Depending on the availability of sulfur, gallium indium‐poor sulfide films consisted on metal‐rich hexagonal β‐GaS layers or stoichiometric amorphous films with E g = 3.0–3.3 eV. Finally, gallium indium‐rich sulfide films formed a mixture of β‐In 2 S 3 and β‐GaS that became near amorphous as more sulfur was supplied; a bandgap energy of E g = 2.44 eV was found. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
Tetragonal crystal system
Deposition
Stoichiometry
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