Efficient catalytic oxidation of primary and secondary alcohols using a non-heme dinuclear iron complex

Alette G.J. Ligtenbarg,P. Oosting,Johannes Roelfes,R.M. La Crois,Martin Lutz,Anthony L. Spek,Ronald Hage,Bernard Feringa

Efficient catalytic oxidation of primary and secondary alcohols using a non-heme dinuclear iron complex

2001

Alette G.J. Ligtenbarg
P. Oosting
Johannes Roelfes
R.M. La Crois
Martin Lutz
Anthony L. Spek
Ronald Hage
Bernard Feringa

A novel μ-oxo diiron(III) complex is capable of fast and selective oxidation of primary and secondary alcohols in the presence of H2O2 and a remarkable increase in reaction rate is achieved by addition of 1 eq. of CF3SO3H.

Keywords:

Galactose oxidase
Heme
Photochemistry
Organic chemistry
Alcohol oxidation
Chemistry
Inorganic chemistry
Catalytic oxidation
Reaction rate
non heme
iron complex

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