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    Synergistic design of a semi-hollow core–shell structure and a metal–organic framework-derived Co/Zn selenide coated with MXene for high-performance lithium–sulfur batteries
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    Abstract:
    Lithium-sulfur batteries have garnered significant interest as potential energy storage systems for the future, owing to their remarkable theoretical specific capacity (1675 mA h g
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    Reactions of alkaline metal carbonates with sulfur are investigated in detail. The evolution of CO and a trace of were observed in the course of reaction with major component of polysulfides. Some evidences that the reaction proceeds with breaking of terminal sulfur-sulfur bond in the sulfur polymer, and forming CO, and polysulfide are presented. Polysulfides have the role of keeping free sulfur and allow it to react with other chemicals to rather high temperatures.plexes, whereas the binuclear and mononuclear complexes of Mn and Co$^{2+}$
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    Polysulfide shuttle of lithium–sulfur batteries can be suppressed by alpha-lipoic acid, an electrolyte additive, which forms a polysulfide rejection layer on sulfur cathode and a stable SEI layer on Li metal anode.
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