Mössbauer Effect of the119Sn in the Molecular Complexes of Tin Tetrachloride with Some Aliphatic Compounds
24
Citation
9
Reference
10
Related Paper
Citation Trend
Abstract:
Abstract Molecular complexes of tin tetrachloride with some aliphatic compounds, such as alcohols and esters, were investigated by means of the Mössbauer effect due to 119Sn, irradiation being made by 23.8 keV γ-rays from the 119mSn in tin dioxide. Most of these complexes show quadru-pole splittings resulting from the addition of organic molecules to tin tetrachloride, although broad absorption curves are observed in some cases. The isomer shifts range from 0.30 to 0.45 mm/sec. They are much smaller than that of tin tetrachloride itself. The results are interpreted by taking account of the electronic structures of the complexes.Keywords:
Tetrachloride
Tin dioxide
Tin dioxide
Deposition
Tin oxide
Pulsed Laser Deposition
Cite
Citations (0)
Abstract Molecular complexes of tin tetrachloride with some aliphatic compounds, such as alcohols and esters, were investigated by means of the Mössbauer effect due to 119Sn, irradiation being made by 23.8 keV γ-rays from the 119mSn in tin dioxide. Most of these complexes show quadru-pole splittings resulting from the addition of organic molecules to tin tetrachloride, although broad absorption curves are observed in some cases. The isomer shifts range from 0.30 to 0.45 mm/sec. They are much smaller than that of tin tetrachloride itself. The results are interpreted by taking account of the electronic structures of the complexes.
Tetrachloride
Tin dioxide
Cite
Citations (24)
Tetrachloride
Cite
Citations (10)
The initial oxidation of two groups of tin structures with different chemical bindings, designated as alpha 2-Sn type and beta -Sn type, simultaneously grown by different electrochemical reductions is investigated by Mossbauer spectroscopy, and partly by X-ray photoelectron spectroscopy. It is shown that during the growth process the tin types become oxidized either to a mixture of tin(II) and tin(IV) oxides, or to tin(IV) oxides, but that the later oxidation in air at room temperature, monitored by periodic Mossbauer studies, is always to tin(IV) oxides. The kinetic results show that the mechanisms of oxidation of the two tin types are almost identical and that, if there is some difference, as suggested by parallel electron diffraction studies, it is beyond the sensitivity of the method. The oxidation of the tin types is a two-stage process, with a very large initial rate of oxidation, which decreases after aging for 1 or 2 months. Numerical equations describing parts of the oxidation curves are derived. The influence of impurities on the oxidation process is discussed.
Oxidation process
Cite
Citations (5)
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTVapor Pressures of Titanium Tetrachloride-Carbon Tetrachloride Mixtures.G. A. Ryder, M. R. Kamal, and L. N. CanjarCite this: J. Chem. Eng. Data 1961, 6, 4, 594–595Publication Date (Print):October 1, 1961Publication History Published online1 May 2002Published inissue 1 October 1961https://pubs.acs.org/doi/10.1021/je60011a033https://doi.org/10.1021/je60011a033research-articleACS PublicationsRequest reuse permissionsArticle Views40Altmetric-Citations2LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
Titanium tetrachloride
Tetrachloride
Silicon tetrachloride
Cite
Citations (2)
Mixtures of carbon tetrachloride with ethers and alcohols attack stainless steels appreciably. This corrosive reaction is especially severe in dry solvents and in the presence of light. Reaction of carbon tetrachloride with ether and alcohol groups, with liberation of hydrogen chloride, also takes place in the absence of metals and should be kept in mind whenever using carbon tetrachloride. The attack by these solvents on stainless-steel high-performance liquid chromatography equipment is considered.
Tetrachloride
Carbon fibers
Hydrogen chloride
Carbon steel
Cite
Citations (9)
Cite
Citations (2)
Tetrachloride
Polarity (international relations)
Carbon fibers
Cite
Citations (16)
Potential health hazards in the chemical vapor deposition of tin oxide films from tetramethylin, dimethylin dichloride, and tin tetrachloride have to be balanced against the benefits to solar cell fabrication. Concerns regarding the toxicity, costs, and physical properties of and the quality of the tin oxide films produced with these tin precursors are outlined. (AIP)
Tetrachloride
Tin oxide
Silicon tetrachloride
Deposition
Cite
Citations (4)
Abstract Abstract The γ-radiolysis of hydrogen sulphide in the presence of : utadiene and carbon tetrachloride was studied. Addition of butadiene causes the slow diminishing in G(H2) and sharp lowering in G(S) from 7.1 for pure H2S down to 0.8 at all the used concentrations of butadiene. When carbon tetrachloride is added to hydrogen sulphide, G(H2) is not changed but G(S) increases by ΔG(S) ≈ 2. The presence of butadiene and carbon tetrachloride together allows to the same change in G(H2) as in the case of butadiene alone and lowering I(S) to zero. The ionic mechanism of molecular sulphur formation is proposed, consistent with the observed experimental facts.
1,3-Butadiene
Carbon fibers
Hydrogen sulphide
Cite
Citations (1)