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    Reductive acetylation of nitro compounds. III. Chemical transformations in three thiophene systems
    Journal of Heterocyclic Chemistry (1975)
    L. H. KlemmWilson Hsin
    Abstract Nitro groups on thiophene ring systems are transformed directly into acetylamino functions in yields of 61–82% by means of a mixture of iron, acetic acid, and acetic anhydride at 50–105°. When a bromo suhstituent is also present on the ring partial hydrodebromination occurs during the reaction.
    Citations (22)
    The practical acetylation of nucleosides using acetic anhydride/acetic acid as a reusable solvent
    Journal of Chemical Research (2022)
    Xia RanChao XiaYing-Xing YangLijie LiuLeishan Chen
    The highly practical acetylation of free nucleosides is achieved using acetic anhydride/acetic acid as a reusable solvent and acetylating regent. A series of nucleosides, including ribosyl, deoxyribosyl, arabinosyl, acyclic and pyranosyl, and many clinical drugs were acetylated efficiently, even on large scale (200 g).
    Citations (1)
    Acetylation of 2-(1-naphthyl)thiophene
    Chemistry of Heterocyclic Compounds (1966)
    N. V. StulinN. I. Putokhin
    Citations (1)
    A Convenient and Chemoselective Acetylation and Formylation of Alcohols and Phenols Using Acetic Acid and Ethyl Formate in the Presence of Bi(III) Salts
    Journal of Chemical Research (2001)
    Iraj Mohammadpoor‐BaltorkAhmad Reza KhosropourHamid Aliyan
    A variety of alcohols are acetylated and formylated efficiently with acetic acid and ethyl formate in the presence of catalytic amounts of Bi(III) salts such as BiCl 3 , Bi(TFA) 3 and Bi(OTf) 3 . BiCl 3 and Bi(OTf) 3 are also effective catalysts for acetylation of phenols. All of these catalysts are ineffective in formylation of phenols. Selective acetylation and formylation of alcohols in the presence of phenols is an additional advantage of this procedure.
    Formylation
    Ethyl formate
    Methyl formate
    Citations (21)
    Effect of the structures of hydroperoxides on the kinetics of their acetylation by acetic anhydride
    Bulletin of the Academy of Sciences of the USSR Division of Chemical Science (1982)
    V. L. AntonovskiĭL. V. ZhitinaO. K. YanaevaYu. D. Emelin
    Pummerer rearrangement
    Citations (0)
    Selective Acetylation of the Primary Hydroxyl Group in Methyl D-Hexopyranosides with a Mixture of Acetic Anhydride and Acetic Acid
    Russian Journal of Bioorganic Chemistry (2021)
    Yury E. TsvetkovDmitry V. YashunskyNikolay E. Nifantiev
    Bioorganic chemistry
    Hydroxyl value
    Primary (astronomy)
    Citations (1)
    Noncatalytic selective 6-O-acetylation of methyl 2,3-di-O-benzoyl-α-d-glucopyranoside with acetic acid and acetic anhydride
    Russian Chemical Bulletin (2020)
    Yury E. TsvetkovMarina L. GeningNikolay E. Nifantiev
    Hydroxyl value
    Acid anhydride
    Citations (2)
    Reductive acetylation of nitro ketones of the thiophene series
    Chemistry of Heterocyclic Compounds (1982)
    Ya. L. Gol'dfarbB. P. FabrichnyiI. F. Shalavina
    Citations (6)
    3. Acetate manufacturing, process and technology 3.1 Chemistry of cellulose acetylation
    Macromolecular Symposia (2004)
    Hans Steinmeier
    Abstract Nowadays Celluloseacetate is mainly produced with the acetic acid process. After an activation with acetic acid and sulfuric acid the acetylation of the cellulose starts by adding acetic anhydride. The temperature and the catalyst concentration play an important role for the reaction. Beneath acetylation also degradation of the cellulose chains occurs. In the first step of the process cellulosetriacetate is formed. In a second step, the hydrolysis, several acetyl groups are removed to achieve an average degree of substitution of 2,5. The water content in this step influences the acetyl distribution.
    Hydroxyl value
    Cellulose acetate
    Degradation
    Citations (71)
    Nitro derivatives of 2-(1-naphthyl) thiophene
    Chemistry of Heterocyclic Compounds (1966)
    N. V. StulinN. I. Putokhin
    Citations (2)