Oxidation and Reduction of Halogen‐containing Compounds
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Abstract The sections in this article are Introduction Anodic Processes Halogenated Alkanes Alicyclic Halides Aryl Halides Cathodic Processes Halogenated Alkanes Halogenated Alkenes and Alkynes Benzyl Halides Alicyclic Halides Aryl Halides Acyl and Phenacyl Halides Aliphatic α‐Halocarbonyl Compounds Halogenated Heterocyclic Compounds Catalytic Reduction of Carbon–Halogen BondsKeywords:
Alicyclic compound
Phenacyl
Aryl halide
Acceptor
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Based on DFT calculations, a new mechanism for the oxidative addition of aryl halides to Pd-catalysts is presented. The key intermediate is an anionic Pd-species in which the aryl halide coordinates to the palladium via the halide atom.
Oxidative addition
Aryl halide
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A new series of chelate stabilized aryl halide coordination complexes of molybdenum are prepared by a novel oxidative addition strategy; quantitative equilibrium measurements suggest that the structure of the chelate ring, rather than the identity of the halide (X = Cl, Br, I), controls the strength of aryl halide binding in these complexes.
Oxidative addition
Aryl halide
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Nine perfluoroacyl fluorides underwent halogen exchange when treated with anhydrous lithium halides to give acyl chlorides, bromides and iodides in high yields. The temperature dependence of this reaction is described. In the reaction with perfluorodiacyl fluoride, the diacyl halides possessing different acyl halide-groups were also produced. Of the alkaline metal salts used halogen exchange was successful only with lithium salts because of the interaction between lithium and fluorine.
Anhydrous
Metal halides
Lithium fluoride
Fluorine
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Abstract The results of the reaction of the phenacyl halides (I) with Ti(III) chloride or sulfate depend on the pH value and the solvent.
Phenacyl
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The reactions of some halogens, interhalogens, and related compounds with the tetra-alkylammonium halides in liquid hydrogen chloride have been investigated. In general, polyhalide ions were formed. The reactions were followed conductometrically.
Hydrogen chloride
Hydrogen halide
Halocarbon
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The thermal decomposition of the halides and basic halides of copper(II) have been studied by a thermogravimetric method. The hydrated chloride loses water and then halogen to give the copper(I) compound which then oxidises to copper(II) oxide; the bromide behaves similarly. The basic chlorides dehydroxylate, then lose halogen, while the basic bromide loses halogen first and then water. The behaviour of the hydrated fluoride and the basic iodide is complicated by the simultaneous loss of water and halogen as hydrogen fluoride or iodine. Activation energies for some of the reactions have also been derived.
Hydrogen fluoride
Thermogravimetric analysis
Hydrogen bromide
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Abstract The sections in this article are Introduction Anodic Processes Halogenated Alkanes Alicyclic Halides Aryl Halides Cathodic Processes Halogenated Alkanes Halogenated Alkenes and Alkynes Benzyl Halides Alicyclic Halides Aryl Halides Acyl and Phenacyl Halides Aliphatic α‐Halocarbonyl Compounds Halogenated Heterocyclic Compounds Catalytic Reduction of Carbon–Halogen Bonds
Alicyclic compound
Phenacyl
Aryl halide
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Abstract Die Gleichgewichtspositionen für die Halogen‐Neuverteilungsreaktionen von Tri‐n‐butylzinnhalogeniden (I) mit einer Vielzahl von strukturell unterschiedlichen Alkylhalogeniden oder Acetylhalogeniden (II) werden bestimmt.
Redistribution
Halogen bond
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