Structural and optical properties of nitrogen-incorporated HfO2 gate dielectrics deposited by reactive sputtering

Abstract High- k HfO x N y thin films with different nitrogen-incorporation content have been fabricated on Si (1 0 0) substrate by means of radio-frequency reactive sputtering method. Analyses from X-ray diffraction (XRD) and atomic force microscopic have indicated that the increase of the crystallization temperature of HfO 2 thin films and the decrease of the roughness root-mean-square value of HfO 2 thin films due to the incorporation of nitrogen. Based on a parameterized Tauc–Lorentz (TL) dispersion model, the optical properties of the HfO x N y thin films related to different nitrogen-incorporation content are systematically investigated by spectroscopic ellipsometer. Increase in the refractive index and the extinction coefficient and reduction in band gap with increase of nitrogen-incorporation content are discussed in detail.