Enrichment of critical elements (Nb-Ta-Zr-Hf-REE) within coal and host rocks from the Datanhao mine, Daqingshan Coalfield, northern China

Abstract This paper discusses the modes of occurrence of critical elements and their origins in the studied coal and associated rock samples (partings and roof strata) from the Datanhao coal mine, Daqingshan Coalfield, Inner Mongolia, northern China. The studied coals are enriched in trace elements including Zr, Hf, Th, Be, F, Zn, Ga, Nb, Mo, Cd, In, Sn, Ta, Hg, W, Pb, and rare earth elements and Y (REY). Zirconium, Nb, Ta, and Hf are largely associated with anatase in the studied coal and non-coal samples. The main carriers of REY, Th, and U in both coal and non-coal samples are Ca-bearing REE-phosphate minerals, most likely monazite, although U is partly associated with organic matter. Fluorine in the Datanhao coals is mainly associated with kaolinite. Most partings identified as volcanic ash-derived tonsteins from the Datanhao Mine exhibit negative Eu anomalies that, along with the common presence of equant-shaped euhedral volcanic quartz (beta-quartz), indicate a felsic volcanic source located in the Xing'an-Mongolia Orogenic Belt. Other probable sources of clastic material into the basin include the pre-Cambrian granites from the adjacent uplands, which may be responsible for the light rare earth element enrichment of the studied deposits, and associated metamorphic rocks from the adjacent uplands. Owing to acidic hydrothermal fluids, which are most likely related to the Yanshanian (Jurassic to Early Cretaceous) intrusive activity and/or low-temperature basinal waters circulating within the coal-bearing unit during the epigenetic stage, most of the coal benches from the Datanhao mine are also relatively enriched in middle rare earth elements. On the other hand, some coal and non-coal bench samples from the middle Datanhao section are enriched in heavy REE. This, along with the presence of abundant syngenetic or early diagenetic carbonate minerals, indicates deposition in an episodic alkaline environment, the origin of which is mostly probably attributed to evaporation and/or saline water inputs resembling a playa lake environment. As the concentrations of Zr, Hf, Nb, and Ta are all close to or higher than the respective industry cut-off grades or standards for these critical elements, the Datanhao coal seam has potential economic significance for these as an important by-product of the coal mining.