Stacking fault, microtopography and thermal decomposition studies of CrxW1−xSe2 (x=0.25, 0.50, 0.75) single crystals

Abstract The single crystals of Cr x W 1− x Se 2 ( x =0.25, 0.50, 0.75) have been grown by the chemical vapour transport (CVT) technique using iodine as a transporting agent. The structural characterisation of these crystals has been made by the X-ray diffraction (XRD) method. The lattice parameters, unit cell volume, crystallite size, strain and dislocation densities have also been evaluated for these new crystals. The estimation of growth and deformation fault probabilities is further calculated. The grown crystals were examined under an optical zoom microscope for their surface topography. Thermo gravimetry analysis (TGA) and differential thermogravimetry (DTG) were carried for the CVT grown Cr x W 1− x Se 2 single crystals. The different kinetic parameters: entropy, enthalpy and Gibbs free energy were calculated using Piloyan–Novikova (P–N) and Coats–Redfern (C–R) relations.