Optimizing two and four-terminal CuGaSe2/CuInGaSe2 tandem solar cells for achieving high efficiencies

Abstract Solar cells based on CuInGaSe 2 (CIGS) have attained the highest record efficiency (22.9%) among thin film solar cells. CIGS is formed by the appropriate mixing of CuInSe 2 (CIS) which has a bandgap around 1 eV and CuGaSe 2 (CGS) which has a bandgap around 1.7 eV. These bandgaps are close to the optimal values for two-junction tandem solar cells. Therefore, CGS on CIGS or CGS on CIS tandem cells should be attractive and viable to achieve high efficiency and cost-effective thin film solar cells. In this work, a simple unified analytical model is used to design two-terminal and four-terminal CGS/CIGS tandem solar cells, establishing a realistic value for the expected efficiency in each case. Short circuit current density (Jsc), open circuit voltage (Voc), fill factor (FF) and efficiency, are determined as a function of the CGS and CIGS acceptor impurity concentrations, back surface recombination velocities, minority carrier diffusion lengths, and absorber layer thickness. It is shown that realistic efficiencies over 30% can be achieved under one sun AM1.5 spectrum for both of the terminal configurations, but the optimum composition for the CIGS sub-cell should be different depending on the respective tandem cell configuration.