Optical and electro-optic properties of micrometric thick lead zirconate titanate films on (Pb0.86,La0.14)TiO3/glass
2009
Highly (100)-oriented Pb(Zr0.52,Ti0.48)O3 (PZT) films of up to ∼2.4 μm are deposited on the (Pb0.86,La0.14)TiO3 (PLT)-coated amorphous substrate by one cycle of sputtering and annealing. The films possess fibrous columnar nanostructures and vertically grow on the PLT/glass substrate. Microstructure analysis and property characterization indicate that the films possess very promising optical, waveguiding, and electro-optic (EO) properties, as well as low propagation loss. The transparency of >80% in the range of λ=400–1200 nm and the linear EO coefficient of 341.4 pm/V have been measured in the films. Due to the large EO coefficient and the micrometric thickness, a giant phase retardation of 2.93 rad has been measured under an electric field of 50 kV/mm.
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