An aqueous non-heme Fe(IV)oxo complex with a basic group in the second coordination sphere

Mads Sørensen Vad,Anders Lennartson,Anne Nielsen,Jeffrey Harmer,John E. McGrady,Cathrine Frandsen,Steen Mørup,Christine J. McKenzie

An aqueous non-heme Fe(IV)oxo complex with a basic group in the second coordination sphere

2012

Mads Sørensen Vad
Anders Lennartson
Anne Nielsen
Jeffrey Harmer
John E. McGrady
Cathrine Frandsen
Steen Mørup
Christine J. McKenzie

The Fe(IV)oxo complex of a coordinatively flexible multidentate mono-carboxylato ligand is obtained by the one electron oxidation of a low spin Fe(III) precursor in water.

Keywords:

Coordination sphere
Spin-½
Heme
Crystal structure
Denticity
Chemistry
Photochemistry
Ligand
Inorganic chemistry
Aqueous solution
non heme

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