THE REDUCTION OF CYCLIC DISULPHIDES WITH TRIARYLPHOSPHINES IN AQUEOUS ORGANIC SOLVENTS

1991 
Abstract The kinetics of the reduction of cyclic disulphides with triphenylphosphine have been studied in aqueous ethanol at various temperatures. Solvent effects on the reaction of 4-phenyl-1,2-dithiolane with tris-(4chlorophenyl) phosphine in a number of aqueous organic solvents have been analysed in terms of the Kirkwood, Y and EN T functions.
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