Structure and electrical properties of (100)-oriented Pb(Zn1/3Nb2/3)O3–Pb(Mg1/3Nb2/3)O3–PbTiO3 thin films on La0.7Sr0.3MnO3 electrode by chemical solution deposition
2008
Abstract (100)-oriented 0.462Pb(Zn 1/3 Nb 2/3 )O 3 –0.308Pb(Mg 1/3 Nb 2/3 )O 3 –0.23PbTiO 3 (PZN-PMN-PT) perovskite ferroelectric thin films were prepared on La 0.7 Sr 0.3 MnO 3 /LaAlO 3 (LSMO/LAO) substrate via a chemical solution deposition route. The perovskite LSMO electrode was found to effectively suppress the pyrochlore phase while promote the growth of the perovskite phase in the PZN-PMN-PT film. The film annealed at 700 °C exhibited a high dielectric constant of 2130 at 1 kHz, a remnant polarization, 2 P r , of 29.8 μC/cm 2 , and a low leakage current density of 7.2 × 10 − 7 A/cm 2 at an applied field of 200 kV/cm. The ferroelectric polarization was fatigue-free at least up to 10 10 cycles. Piezoelectric coefficient, d 33 , of 48 pm/V was also demonstrated. The results showed that much superior properties could be achieved with the PZN-PMN-PT thin films on the solution derived LSMO electrode than on Pt electrode by sputtering.
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