The heat capacity and derived thermodynamic functions of La2Zr2O7 and Ce2Zr2O7 from 4 to 1000 k

Abstract The heat capacities of cerium and lanthanum zirconate (Ce 2 Zr 2 O 7 and La 2 Zr 2 O 7 ) were measured from 4 to 400K by adiabatic calorimetry. The derived thermodynamic functions, H °, S ° and {G ° − H °(0)} T were calculated. The standard molar entropies at 298.15K were determined as 230.21 ± 0.46 J/mol · K and 238.53 ± 0.48 J/mol · K. Enthalpy increments relative to 298.15 K were measured by drop calorimetry from 500 to 900 K. From these data the thermodynamic functions, including the enthalpy and Gibbs free energy of formation of the two compounds were derived for temperatures up to 1000 K.