Synthesis of fluorine-containing tetraketones and diketo esters and luminescence-spectral properties of their complexes with lanthanide ions
2006
The Claisen condensation of diesters of fluorinated dicarboxylic acids with 2-acetyl-naphthalene affords the corresponding naphthyl-containing tetraketones and diketo esters. The luminescence-spectral properties and stability constants of complexes of these compounds with Eu3+ ions were estimated. The characteristics of the complexes are comparable with those of fluorinated β-diketones containing chromophoric substituents, which are widely used in luminescence analysis. The synthesized naphthyl-containing diketo esters are efficiently conjugated with proteins and can be used for detection of biospecific interactions.
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