Preparation of Hierarchical Porous Activated Carbon from Banana Leaves for High‐performance Supercapacitor: Effect of Type of Electrolytes on Performance

2020 
We demonstrate a facile efficient way to fabricate activated carbon nanosheets (ACNSs) consisting of hierarchical porous carbon materials. Simply heating banana leaves with K2CO3 produce ACNSs having a unique combination of macro-, meso- and micropores with a high specific surface area of ~1459 m2g-1. The effects of different electrolytes on the electrochemical supercapacitor performance and stability of the ACNSs are tested using a two-electrode system. The specific capacitance (Csp) values are 55, 114, and 190 Fg-1 in aqueous 0.5 M sodium sulfate, organic 1 M tetraethylammonium tetrafluoroborate in acetonitrile, and pure ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]) electrolytes, respectively. The ACNSs also shows the largest potential window of 3 V, the highest specific energy (59 Whkg-1) and specific power (750 Wkg-1) in [BMIM][PF6]. A mini-prototype device is prepared to demonstrate the practicality of the ACNSs.
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