Synthetic application of a substituent controlled Claisen rearrangement: preparation of advanced chiral intermediates for the synthesis of pseudomonic acids

Dennis P. Curran,Suh Young-Ger

Synthetic application of a substituent controlled Claisen rearrangement: preparation of advanced chiral intermediates for the synthesis of pseudomonic acids

1984

Dennis P. Curran
Suh Young-Ger

Abstract A substituent controlled Claisen rearrangement is employed as the key reaction for a facile construction of chiral intermediates for the synthesis of pseudomonic acids from diacetyl-L-arabinal.

Keywords:

Photochemistry
Sigmatropic reaction
Carroll rearrangement
Chirality (chemistry)
Bicyclic molecule
Organic chemistry
Chemistry
Glycal
Claisen rearrangement
Substituent
Stereochemistry

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