Preparation and characterization of graphitic carbon nitrides/polyvinylidene fluoride adsorptive membrane modified with chitosan for Rhodamine B dye removal from water: Adsorption isotherms, kinetics and thermodynamics

Abstract In the present study, a PVDF/g-C3N4/chitosan (PCC) membrane was used for the removal of Rhodamine B from aqueous solutions. Water flux for PCC membrane decreased from 49.87% to 14.76% by the addition of chitosan from 2% to 4%. Afterward, batch adsorption conditions were optimized for a PVDF/g-C3N4/chitosan membrane applying Box-Behnken design algorithm. The maximum RB removal efficiency was 72.74% at 2 mg/L of initial RB concentration, pH = 3, 2 g of g-C3N4 and 3% of chitosan at the optimum conditions. The Freundlich isotherm and pseudo-second order models were satisfactorily describing the equilibrium and kinetic of adsorption, respectively. Thermodynamic parameters were disclosed that the adsorption of RB onto PCC was exothermic (ΔH° = −21.35 kJ mol−1) and spontaneous (ΔG°