The Pedogenesis of Soil Derived from Carbonate Rocks along a Climosequence in a Subtropical Mountain, China

Revealing the pedogenesis of soil on carbonate rocks is a key step in determining the boundaries of soil types along a climosequence. However, related research is lacking for a subtropical mountain. In this study, eight pedons were sampled across an elevation gradient (789–2322 m) having large variation in mean annual precipitation (MAP) (1189–1764 mm) and mean annual temperature (MAT) (5.7–14.9 °C). General processes were performed, including physical, chemical, and morphological characterizations, X-ray diffraction (XRD), total elements’ content, and soil classification of the carbonate rock. In the climo-toposequence, the illite had been transformed into illite-smectite below 1300–1500 m of elevation, 1300–1370 mm of MAP, and above 10.5–11.5 °C of MAT, and into vermiculite above this climate. These findings indicated that the effects of temperature on soil mineral transformation had weakened with the gradual increases in elevation. The pedon at 861 m of elevation, 1206 mm of MAP, and 14.5 °C of MAT, which accounted for the argic horizons, was divided into Argosols after human activities. The finding revealed that changes from forest to cultivated land could potentially accelerate the formation of argic horizons, and it provided a theoretical basis for global carbonate rocks’ weathering conditions and ecological problems in subtropical mountains. When the soils reached approximately 1100–1200 m of elevation, 1250–1300 mm of MAP, and 11.5–13.5 °C of MAT, the argic horizons of the soil could be accounted for, as evolved from the Cambosols in Chinese Soil Taxonomy (CST) (Inceptisols in Soil Taxonomy (ST), Cambisols in the World Reference Base for Soil Resources (WRB)) to the Argosols in CST (Alfisols in ST, Luvisols or Alisols in WRB) under natural vegetation. Therefore, it was indicated that the soil types changed significantly in the CST, ST, and WRB with increases of MAP and decreases of MAT, which provides a reference for determining the boundaries of the soil types along a climosequence in subtropical mountains.