The occurrence, soil parameters and genesis of rubified soils (‘Fuchserden’) of northeastern Germany

Abstract The local occurrence of red subsoils on the Late Pleistocene sandy deposits of the Northern European lowlands invites investigation into the formation and paleoenvironmental significance of these soils. According to the World Reference Base for Soil Resources (WRB), these soils are classified as Rhodic Brunic Arenosols or Chromic Brunic Arenosols; however, because of their unclear origins, these soils are still not considered in the German Guidelines for Soil Mapping. We aim to characterize the genesis of these rubified soils by combining pedological findings with chemical analyses and micromorphological studies at four sites in southeastern Brandenburg, Germany. Our novel analytical approach differentiates pedogenic iron (hydr-)oxides using a combination of Fourier transform infrared-multiple internal reflection (FTIR-MIR) spectroscopy and sequential sample heating (from 21 °C to 100 °C, 250 °C, 500 °C, and 950 °C). Together with a comparison of synthetic iron (hydr-)oxides, the results of this analytical approach demonstrate that the mineralogy of these Rhodic Brunic Arenosols and Chromic Brunic Arenosols are characterized mainly by hematite; some goethite and minor amounts of maghemite are also present. Our results confirm recent findings from Jankowski (2013) that rubification is not primarily a relict process in Central European soils; consequently, the German Guidelines for Soil Mapping require revision. The high total iron contents in the rubified soils suggest strongly that the iron is allochthonous in origin, emphasizing the importance of lateral inputs of iron compounds in the genesis of these soils. This finding is highly consistent with the ‘translocation catena ’ concept ( Sommer and Schlichting, 1997 ); i.e., the Rhodic Brunic Arenosols and Chromic Brunic Arenosols studied here formed due to inputs of allochthonous compounds. These rubified soils examined in this study share some genetic features with other soils described from Central Europe, such as the ‘Lockerbraunerden’ or the ‘Ockererden’. Further research should focus on these commonalities and compare the genetic pathways of such soils to support the argument that these soils should be considered in a separate soil class in the German Guidelines for Soil Mapping.