Solvent Effect on the Hammett Reaction Constant of Substituted Benzoic Acids
1993
Potentiometric titration has been used to measure dissociation constants of 13 monosubstituted benzoic acids in nitromethane, benzonitrile , acetonitrile , propylene carbonate, acetone, N,N-dimethylformamide, dimethyl sulfoxide, methanol and formamide. The reaction constants of the Hammett equation were found to depend on the solvent acidity and basicity expressed by the α and β parameters of Kamlet and Taft. The p values determined earlier in water and ethanol also obey this rule.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
0
References
16
Citations
NaN
KQI