Spectroscopic states and dissociation of negative molecular ions. Communication 3. An investigation of 1,2-dihydro-3h-1,4-benzodiazepin-2-ones
1987
1.
E- and Z-conformations of 1,2-dehydro-3H-1,4-benzodiazepin-2-ones are realized in the gas phase and in solution as the result of the inversion of the seven-membered ring.
2.
The Z-conformers possess weak physiological activities or none at all.
3.
The activities of the E-conformers depend on the ionization potentials of the unshared electron pairs of the nitrogen atoms of the seven-membered heterocycle by a logarithmic law.
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