Multifunctional Role of MoS2 in Preparation of Composite Hydrogels: Radical Initiation and Cross-Linking

This paper describes the multifunctional effect of molybdenum disulfide (MoS2) that enables the rapid and accessible preparation of nanocomposite hydrogels via a bottom-up design. The MoS2 nanoplatelet forms radical species through a redox reaction with persulfate under aqueous conditions while initiating the polymerization of acrylic monomers and providing non-covalent cross-linking points without requiring external stimuli or extra cross-linkers, leading to the formation of hydrogels that are in situ embedded with inorganic flakes. Furthermore, the addition of MoS2 could induce more rigid and elastic networks compared to those in control hydrogels using a typical cross-linker at the same level; for example, 0.08 wt% MoS2 resulted in a composite hydrogel of which the elastic modulus was 2.5 times greater than that from a hydrogel using N,N′-methylenebis(acrylamide) as the showing phase transition during polymerization. The composite hydrogels are self-healable, taking advantage of reversible physical cro...