Fabrication of thiophene-chitosan hydrogel-trap for efficient immobilization of mercury (II) from aqueous environs

Abstract The fabrication of thiophene–chitosan (TCS) hydrogel has been carried out to show the excellent binding performance of Hg(II) from an aqueous solution of heavy metal ions in presence of thiophene moiety within the hydrogel network. Thiophene moiety has been implanted within chitosan, a wild bio-resources, through a facile Schiff base condensation strategy with 2-thiophenecarboxaldehyde to develop a three-dimensional network of TCS hydrogel. The parameters influencing adsorption capacity such as pH, volume of functional agent, contact time, amount of the hydrogel are included to broaden the in-depth study for the adsorption window of Hg(II) followed by the desorption and reusability performance of TCS. The results indicate that the TCS hydrogel for Hg(II) followed pseudo-second-order kinetics. Ethylenediaminetetraacetic acid (EDTA), acts as a better eluent compared to HCl to desorb Hg(II) and even after recurring adsorption/desorption cycles, removal efficacy of TCS hydrogel could be retained.