Synthesis of novel macrobicyclic polyfunctional cryptands
1985
Abstract A pathway yielding both syn and anti -functionalized macrocycles derived from bis-tartaro-18-crown-6 (1) as well as a selective route to syn compounds have been developed and applied to the synthesis of new macrobicyclic polyether cryptands ( 2 ) and ( 3 ), which may also be obtained by direct bridging of the dianhydride ( 4 ).
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