Interfacial Properties of Nonionic Hybrid Surfactant with Double Branches of Fluorocarbon and Hydrocarbon

Abstract To obtain superior surface-active properties while minimizing environmental risks, new fluorinated surfactants (F2HX-nEO) were designed to include a hybrid multi-chain with a short fluorocarbon (–CF2CF3) and nonionic ethylene oxide. They were simply synthesized by a straightforward reaction involving the addition of ethylene oxide to a hybrid fluorine alcohol, and their surface-active properties were optimized by controlling the hydrocarbon length and number of ethylene oxide units. Therefore, the desirable values of critical micelle concentration (0.3 mmol/L) and surface tension (24.3 mN/m) were obtained in spite of containing the short fluorocarbon chain. Particularly, F2HX–nEO showed excellent wetting properties on hydrophobic surfaces and very low toxicity level, which can be used in various fields as a promising alternative to long fluoroalkyl chain surfactants.