Fluorocarbons, sometimes referred to as perfluorocarbons or PFCs, are, strictly speaking, organofluorine compounds with the formula CxFy, i.e. they contain only carbon and fluorine, though the terminology is not strictly followed.Compounds with the prefix perfluoro- are hydrocarbons, including those with heteroatoms, wherein all C-H bonds have been replaced by C-F bonds.Fluorocarbons can be perfluoroalkanes, fluoroalkenes and fluoroalkynes and perfluoroaromatic compounds. Fluorocarbons and their derivatives are used as fluoropolymers, refrigerants, solvents, and anesthetics.Carbon tetrafluoride, the simplest perfluoroalkanePerfluorooctane, a linear perfluoroalkanePerfluoro-2-methylpentane, a branched perfluoroalkanePerfluoro-1,3-dimethylcyclohexane, a cyclic perfluoroalkanePerfluorodecalin, a polycyclic perfluoroalkanePerfluoroisobutene, a reactive and highly toxic fluoroalkene gasTetrafluoroethylene, an important perfluorinated monomer.Hexafluoropropylene, another important perfluoroalkene.Hexafluoro-2-butyne, a perfluoroalkyne.Hexafluorobenzene Fluorocarbons, sometimes referred to as perfluorocarbons or PFCs, are, strictly speaking, organofluorine compounds with the formula CxFy, i.e. they contain only carbon and fluorine, though the terminology is not strictly followed.Compounds with the prefix perfluoro- are hydrocarbons, including those with heteroatoms, wherein all C-H bonds have been replaced by C-F bonds.Fluorocarbons can be perfluoroalkanes, fluoroalkenes and fluoroalkynes and perfluoroaromatic compounds. Fluorocarbons and their derivatives are used as fluoropolymers, refrigerants, solvents, and anesthetics. Perfluorocarbons or PFCs are, strictly speaking, organofluorine compounds with the formula CxFy, i.e. they contain only carbon and fluorine, though the terminology is not strictly followed.Compounds with the prefix perfluoro- are hydrocarbons, including those with heteroatoms, wherein all C-H bonds have been replaced by C-F bonds. Fluorocarbons can be divided into perfluoroalkanes, fluoroalkenes and fluoroalkynes or perfluoroaromatic compounds. Perfluoroalkanes are very stable because of the strength of the carbon–fluorine bond, one of the strongest in organic chemistry.Its strength is a result of the electronegativity of fluorine imparting partial ionic character through partial charges on the carbon and fluorine atoms, which shorten and strengthen the bond through favorable covalent interactions. Additionally, multiple carbon–fluorine bonds increase the strength and stability of other nearby carbon–fluorine bonds on the same geminal carbon, as the carbon has a higher positive partial charge. Furthermore, multiple carbon–fluorine bonds also strengthen the 'skeletal' carbon–carbon bonds from the inductive effect. Therefore, saturated fluorocarbons are more chemically and thermally stable than their corresponding hydrocarbon counterparts, and indeed any other organic compound. They are susceptible to attack by very strong reductants, e.g. Birch reduction and very specialized organometallic complexes. Fluorocarbons are colorless and have high density, up to over twice that of water. They are not miscible with most organic solvents (e.g., ethanol, acetone, ethyl acetate, and chloroform), but are miscible with some hydrocarbons (e.g., hexane in some cases). They have very low solubility in water, and water has a very low solubility in them (on the order of 10 ppm). They have low refractive indices. As the high electronegativity of fluorine reduces the polarizability of the atom, fluorocarbons are only weakly susceptible to the fleeting dipoles that form the basis of the London dispersion force. As a result, fluorocarbons have low intermolecular attractive forces and are lipophobic in addition to being hydrophobic and non-polar. Reflecting the weak intermolecular forces these compounds exhibit low viscosities when compared to liquids of similar boiling points, low surface tension and low heats of vaporization. The low attractive forces in fluorocarbon liquids make them compressible (low bulk modulus) and able to dissolve gas relatively well. Smaller fluorocarbons are extremely volatile. There are five perfluoroalkane gases: tetrafluoromethane (bp −128 °C), hexafluoroethane (bp −78.2 °C), octafluoropropane (bp −36.5 °C), perfluoro-n-butane (bp −2.2 °C) and perfluoro-iso-butane (bp −1 °C). Nearly all other fluoroalkanes are liquids; the most notable exception is perfluorocyclohexane, which sublimes at 51 °C. Fluorocarbons also have low surface energies and high dielectric strengths. In the 1960s there was a lot of interest in fluorocarbons as anesthetics. The research did not come to anything, but a lot of effort was expended on the vital issue of flammability, and showed that the tested fluorocarbons were not flammable in air in any proportion, though most are in neat oxygen and neat nitrous oxide (gases of importance in anesthesiology). In 1993, 3M considered fluorocarbons as fire extinguishants to replace CFCs. This extinguishing effect has been attributed to their high heat capacity, which takes heat away from the fire. It has been suggested that an atmosphere containing a significant percentage of perfluorocarbons on a space station or similar would prevent fires altogether.When combustion does occur, toxic fumes result, including carbonyl fluoride, carbon monoxide, and hydrogen fluoride. Perfluorocarbons dissolve relatively high volumes of gases. The high solubility of gases is attributed to the weak intermolecular interactions in these fluorocarbon fluids. The table shows values for the mole fraction, x1, of nitrogen dissolved, calculated from the Ostwald coefficient, at 298.15 K (25 °C), 0.101325 M Pa.