Structural characterisation of Cu2.04Zn0.91Sn1.05S2.08Se1.92
2015
Quaternary Cu2ZnSn(S1-xSex)4 compounds are promising semiconductor materials for absorber layer in thin film solar cells. Record efficiency devices (12.6%) exhibit an off-stoichiometric composition of the absorber layer. These deviations from stoichiometry cause intrinsic point defects, which determine the electronic properties of the semiconductor significantly. A structural analysis of a nearly C-type off-stoichiometric Cu and Sn rich and Zn poor Cu2ZnSn(S1-xSex)4 mixed crystal with x=0.48 by a neutron diffraction investigation was performed. The average neutron scattering length method was applied, showing that the mixed crystal adopts the kesterite type structure. A detailed cation distribution analysis revealed the occurrence of ZnCu(2a) and SnZn anti-site point defects additional to the Cu-Zn disorder in the planes at z=1/4 and 3/4. (© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)
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