Thermodynamics, kinetics, and mechanism of (silox)3M(olefin) to (silox)3M(alkylidene) rearrangements (silox = tBu3SiO; M = Nb, Ta).

Kurt F. Hirsekorn,Adam S. Veige,Michael P. Marshak,Yelena Koldobskaya,Peter T. Wolczanski,Thomas R. Cundari,Emil B. Lobkovsky

Thermodynamics, kinetics, and mechanism of (silox)3M(olefin) to (silox)3M(alkylidene) rearrangements (silox = tBu3SiO; M = Nb, Ta).

2005

Kurt F. Hirsekorn
Adam S. Veige
Michael P. Marshak
Yelena Koldobskaya
Peter T. Wolczanski
Thomas R. Cundari
Emil B. Lobkovsky

Article discussing the thermodynamic, kinetic, and mechanism of (silox)3M(olefin) to (silox)3M(alkylidene) rearrangements (silox = tBu3SiO; M = Nb, Ta).

Keywords:

Reaction rate constant
Olefin fiber
Reaction mechanism
Organic chemistry
Inorganic chemistry
Chemistry
thermodynamic model
Kinetics
Norbornene
2-Norbornyl cation

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