Biocompatible, large-format, inkjet printed heterostructure MoS 2 -graphene photodetectors on conformable substrates

An inkjet printed, biocompatible, heterostructure photodetector is described that was constructed using inks of photo-active molybdenum disulfide (MoS2) and electrically conducting graphene which facilitated charge collection of the photocarriers. The importance of such devices stems from their potential utility in age-related-macular degeneration, which is a condition where the photosensitive retinal tissue degrades with aging, eventually compromising vision. The absence of effective therapeutic remedies for patients with this disorder has motivated the development of such devices to restore some degree of visual function. Inkjet printed, flexible prosthetic devices offer design simplicity where additive manufacturing can enable large format, low-cost arrays. The biocompatible inkjet printed two-dimensional heterojunction devices were photoresponsive to broadband incoming radiation in the visible regime, and the photocurrent I ph scaled proportionally with the incident light intensity, exhibiting a photoresponsivity R ~ 0.30 A/W. This is 103 times higher compared to prior reports, and detectivity D was calculated to be ~3.6 × 1010 Jones. Strain-dependent measurements were also conducted with bending, indicating the feasibility of such devices printed on flexible substrates. Drop cast and printed CT-MoS2 inks were characterized using techniques, such as Raman spectroscopy, photoluminescence measurements and scanning electron microscopy. Both mouse embryonic fibroblast and human esophageal fibroblast were used for the biocompatibility analysis for inks drop cast on two types of flexible substrates, polyethylene terephthalate and polyimide. The biocompatibility of inks formed using two-dimensional graphene and MoS2 on polyimide substrates was extremely high, in excess of 98% for mouse embryonic fibroblast.