Molecular Tunability of Magnetic Exchange Bias and Asymmetrical Magnetotransport in Metalloporphyrin/Co Hybrid Bilayers

Individual molecular spins are promising quantum states for emerging computation technologies. The “on surface” configuration of molecules in proximity to a magnetic film allows control over the orientations of molecular spins and coupling between them. The stacking of planar molecular spins could favor antiferromagnetic interlayer couplings and lead to pinning of the magnetic underlayer via the exchange bias, which is extensively utilized in ultrafast and high-density spintronics. However, fundamental understanding of the molecular exchange bias and its operating features on a device has not been unveiled. Here, we showed tunable molecular exchange bias and its asymmetrical magnetotransport characteristics on a device by using the metalloporphyrin/cobalt hybrid films. A series of the distinctive molecular layers showcased a wide range of the interfacial exchange coupling and bias. The transport behaviors of the hybrid bilayer films revealed the molecular exchange bias effect on a fabricated device, repre...