A model for the cooperative adsorption of surfactant mixtures on solid surfaces

Abstract Adsorption of surfactant mixtures on solids is of considerable theoretical and practical importance. In this study, cooperative adsorption of surfactant mixtures of nonyl phenol ethoxylated decyl ether (NP-10) and n -dodecyl- β - D -maltoside (DM) on silica and alumina has been investigated as a function of the distribution of individual surfactants between solution and solid surface. In the mixed adsorption process, DM is identified to be the “active” adsorbing component and NP is the “passive” co-adsorbing one in the process of adsorption on alumina, while their roles are reversed on silica. A modified model has been proposed to quantify the adsorption behavior of surfactant mixtures and to obtain information in terms of aggregation number and standard free energy for surface aggregation. This model is the first model applied to the aggregation of the surfactant mixture at the solid/solution interfaces.