FDTD Simulations on Plasmonic Properties of End-to-End and Side-by-Side Assembled Au Nanorods

The surface plasmon resonance( SPR) of gold( Au) nanorod can be tuned in a large visible-near infrared( Vis-NIR) region by changing the aspect ratio of nanorod. Compared with the SPR of isolated Au nanorod,assembly of Au nanorods exhibits strong coupling effect in the nanogap and wealthy changes in the optical spectra. The SPR coupling effects and localized electronic fields for end-to-end( E-E) and side-by-side( S-S) assembled Au nanorods dimers are studied through finite-difference time-domain( FDTD) simulation. With decreasing the gap spacing,the longitudinal SPR( SPRL) red-shifts for the E-E orients Au nanorods dimer and blue-shifts for S-S orientes Au nanorods dimer. The transverse SPR( SPRT) has slight red-shifting for S-S assembly and no shifting for the E-E assembly. Moreover,a new coupling SPR appears for the E-E assembly in a long wavelength in the NIR region,blue-shifting and enhancing with decreasing the gap spacing. Based on the spring oscillator model and the polarization of nanoparticles with incident electric field,the SPR shifting and the appearance of new coupling SPR of assembled Au nanorods are proposed.