Diastereoselective cyclopropanation of cyclic enones with methyl dichloroacetate anion
2001
Abstract The reaction of α,β-unsaturated cyclic ketones with methyl dichloroacetate anion in the presence of DBU leads to the corresponding bicyclic chlorocyclopropanes in a highly diastereoselective fashion. In the cases of 2-cyclopentenone and 2-cyclohexenone the reaction affords exclusively the endo -Cl isomer.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
33
References
13
Citations
NaN
KQI