Abstract The pH value of lake water varies with the lake environment, which has an effect on the form of phosphorus in sediment, and then the release of sediment phosphorus. The form of phosphorus in sediments was analyzed using field sampling. The environmental conditions with pH values of 4.0, 7.0 and 10.0 were simulated indoors to estimate the effects of pH on phosphorus release from sediments and the content change of various forms of phosphorus was studied. The results showed that in Wuliangsuhai Lake, Ca-P accounted for 54.3%, which was the largest portion of the TP. Phosphorus release was favored under acidic and alkaline conditions, and the alkaline condition was more favorable. The proportion of Fe/Mn-P and Fe/Al-P in the TP decreased with an increase in the pH, while the proportion of Ca-P in the TP increased with an increase in the pH. Under the alkaline condition (pH = 10), Ca-P in the sediment increased significantly, with an increase of 22.5%. However, Fe/Mn-P and Fe/Al-P decreased significantly, with drops of 37.3% and 44.9%, respectively. Under the acidic condition (pH = 4), Fe/Mn-P and Fe/Al-P in the sediment increased significantly, and the increases were 63.1% and 37.1%, respectively. However, Ca-P decreased significantly, with a drop of 39.2%. In general, low pH promoted the release of Ca-P, and a high pH promoted the release of Fe/Mn-P and Fe/Al-P. Wuliangsuhai Lake water is characterized by weak alkaline characteristics throughout the year, and biological available phosphorus accounts for 13.3%–20.9% of the TP, with Fe/Mn-P being the dominant form. This study revealed that the risk of phosphorus release from sediments to the overlying water was greater under alkaline conditions.
Overlying water and sediment samples were collected from 11 locations in Ulansuhai Lake in June of 2012 to determine the concentration of dissolved inorganic phosphorus (DIP) in the interstitial water, overlying water and sediment and to estimate the diffusion flux of DIP at the sediment–water interface. The DIP levels in overlying water were 0.004–0.185 mg/L (average = 0.062 mg/L), while they were 0.05–0.25 mg/L (average = 0.124 mg/L) in the interstitial water in the 0–2 cm surface sediment. Moreover, the annual mean exchange flux of DIP in the sediment was between −0.092 mg/m2·d and 0.053 mg/m2·d, and this occurred via internal source action in most areas. After area weighting, it is estimated that the exchange capacity of DIP at the sediment–water interface of the Ulansuhai Lake is 1.30 t/a. These findings indicate internal loading of phosphorus in sediment of the Ulansuhai Lake; thus, the diffusion of DIP in the interstitial water has effects on the lake, with a degree of influence of 2.7% to 81.5%.
Abstract In order to investigate the historical water quality state and identify the factors causing modern environmental degradation in a prairie lake, total organic carbon (TOC), total nitrogen (TN), stable carbon isotopes of organic matter and total phosphorus (TP) from lake sedimentary core with high resolution age frame were analyzed. The results show that the values of proxies (TOC, TN, TP, δ13C, C/N) increased significantly after 2000 compared with before, which indicates Lake Hulun has heightened nutrient level and pollution extent, thus induced growth of algal bloom and water quality deteriorated after 2000. Since the event of decreased river discharge and lowered water level began in 2000 corresponds extremely well with our sedimentary records that nutrients pollution and eutrophication occurred in Lake Hulun at the same moment, the change of river discharge can be seen as the primary and direct reason of lake water quality deterioration in this period. In addition, the increased wind and water erosion as a result of serious and widespread destruction of grassland in Lake Hulun basin is the potential factors for changing the nutrients concentration in Lake Hulun.
Microplastic pollution in aquatic environments is characterized by hard degradation, easy mobility, and great harm, making it an important subject of recent research. Deposition, a major microplastic migration process in lakes, to date has been predominantly studied via laboratory experiment and model simulation. To quantify deposition in real-life contexts, therefore, we developed a new experimental method. Specifically, we designed a microplastic trap, based on the similarities and differences between microplastics and naturally occurring suspended solids, to determine the deposition of different size, density, and shaped microplastics in the shallow lake Ulansuhai. Using this new infrastructure at three experiment sites, we found that the deposition flux for all types of microplastic showed good agreement with wind speed. Furthermore, we found that, when density and shape were held constant, larger microplastic pieces were more likely to be deposited, while smaller pieces were more likely to be transported. When size and density were held constant, fragmentary microplastic was more likely to be deposited than fibrous microplastic. And, when size and shape where held constant, higher density microplastic was more likely to be deposited than lower density microplastic. Our method offers a potentially valuable way for exploring the deposition of microplastics in other shallow lakes.
Hulun Lake is the largest lake in northeastern China, and its basin is located in China and Mongolia. This research aims to analyze the dynamic changes in the water volume of Hulun Lake and to estimate the groundwater recharge of the lake during the past 60 years. Multi-source data were used, and water-level-data-interpolation extrapolation, water-balance equations, and other methods were applied. The proportion of the contribution of each component to the quantity of water in Hulun Lake during the last 60 years was accurately calculated. Evaporation loss was the main component in the water loss in Hulun Lake. In the last 60 years, the average annual runoff into the lake was about 1.202 billion m3, and it was the factor with the largest variation range and the leading factor affecting the changes in the quantity of water in Hulun Lake. There was groundwater recharge in Hulun Lake for a long period, and the average annual groundwater recharge was about 776 million m3 (excluding leakage). The contribution ratio of the river water, groundwater, and precipitation to the recharging of Hulun Lake was about 5:3:2. The changes in the quantity of water in Hulun Lake are affected by climate change and human activities in China and Mongolia, especially those in Mongolia.