Paper-based packaging with barrier effect, as opposed to single use plastics, is gaining more prominence for sustainability reasons. At the same time, latex- or biopolymer-based aqueous barrier coating dispersions are increasingly being adopted as a better alternative to the traditional barrier coating materials, such as wax, surface active chemicals, and polyethylene. In this work, studies were performed to determine the influence of different kaolin clays in latex binder-based aqueous coatings on barrier properties, namely, oil and grease, water resistance, and water vapor transmission rate, by applying coatings to solid bleached sulfate (SBS) paperboard substrate in the laboratory. The aim was to explore potential benefits of using kaolin clay to replace some of the latex binder in coating and improve or maintain various types of barrier performance and blocking without negatively influencing the other performance attributes, including heat seal. The delaminated clay with the highest shape factor provided improved barrier properties over the clays of low shape factor. The ultrafine and non-delaminated clays required significantly higher coat weights to reach satisfactory barrier properties. Coatings with different latex levels indicated that a considerably high proportion of coarse delaminated clay can be incorporated to replace latex binder, while still achieving exceptional barrier properties. Furthermore, a change in binder system was found to significantly alter the barrier properties and the role that a mineral pigment can play. The results indicate that a proper selection of binder systems for each barrier property would be required while considering the clay/latex coating systems.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIntercalated metal-clay catalysts in direct liquefaction of bituminous coalLevent Artok, Prakash B. Malla, Sridhar Komarneni, and Harold H. SchobertCite this: Energy Fuels 1993, 7, 3, 430–431Publication Date (Print):May 1, 1993Publication History Published online1 May 2002Published inissue 1 May 1993https://pubs.acs.org/doi/10.1021/ef00039a016https://doi.org/10.1021/ef00039a016research-articleACS PublicationsRequest reuse permissionsArticle Views100Altmetric-Citations10LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
A series of silica xerogels were synthesized in a closed system by hydrolyzing tetramethyl orthosilicate (TMOS) with various concentrations of hydrochloric acid solution but without the addition of alcohol. The molar ratio of H 2 O to TMOS was fixed at 4.96. The gels were characterized by water and nitrogen sorption measurements. The gelation time peaked at 50 to 80 h with 5 × 10 −2 to 10 −1 M HCl, apparently a consequence of the isoelectric point of silica. Surface area, pore size, and sorption capacity were, however, at a minimum for samples prepared with 5 × 10 −2 to 10 −1 M HCl. The BET c constant and hence the net heats of sorption were at a maximum for these samples. Although water sorption of all the samples prepared with HCl exhibited moderate Type I isotherms, the concavity of the isotherms to the P/P 0 axis increased with increasing concentrations of HCl up to 10 −1 M in accordance with the decreased pore size and increased heat of sorption. Addition of F − ions (HF or NaF) in the presence of 10 −1 M HCl steadily decreased the gelation time. Addition of F − in the absence of HCl, however, caused rapid gelation and an increase in pore size, nitrogen BET surface area, and hydrophobicity. Consequently, the shape of water isotherms gradually converted to Type IV and/or Type V. Adsorption and desorption measurements on differently activated gels exhibited various types of hystereses as a result of development of hydrophobie sites at as low as 200°C, inelastic distortion induced by adsorption, and chemical reaction and aging of gels when exposed to water vapor.
Context: Software testability, which is the degree to which a software artifact facilitates process of testing, is not only the indication of the test process effectiveness but also gives the new perspective on code development. Since more than fifty percent of total software development costs is related to testing process activities, Software testability has always been the improving area in software domain so that we can make the software development process effective with respect to test cases writing and fault detection process. Objectives: The research though this thesis will have the objective of proposing a conceptual framework considering the testability issues for the simpler test suite generation and facilitating the concerned persons with better effectiveness of testing. We investigate the testability factors and testability metrics basically with the help of the systematic literature review and the proposed framework’s feasibility is evaluated with case study. Methods: Initially, we conduct the literature review to get broad knowledge on this domain as well for the key documents. Then study starts with the systematic literature review process guided by the review protocol to collect the testability factors and measurements. The framework is validated with the case study. The research documents are included from highly trusted e-database including Compendex, Inspec, IEEE Xplore, ACM Digital Library, Springer Link and Scopus. Altogether 36 primary documents are included for the study and results are extracted. Results: From the results of systematic literature review, Software testability factors and associated measurements are found and the construction of framework for simple test generation as guidelines evaluate with case study. To make the test suite generation simpler, we propped a framework based on the FTA concepts and breakdown of high level testability factors to its simpler form of measureable level. Conclusions: Numbers of different software testability factors are presented in different researches in different perspectives. We collect important testability factors and associated measurement methods and we concluded the effect of testability in simpler test suite generation with the help of framework evaluated by case study.
