Locally produced methane, - either as biomethane or power-to-gas product, has to be stored to provide a reliable gas source for the fluctuating demand of any local gas distribution network. Additionally, methane is a prominent transportation fuel but its suitability for vehicular application depends on the ability to store an adequate amount in the onboard fuel tank. Adsorption in porous materials could enable a simple, safe and cost-effective method for storing methane at ambient temperature and at reasonably low pressure. In this project we study and test the main thermodynamic and kinetic characteristics of methane adsorption and desorption on activated carbon. Both calculations and measurements are performed to enhance our knowledge about the general performance and the cyclic behavior of the adsorption and desorption processes.
The intermittency of renewable energy technologies requires adequate storage technologies. Hydrogen systems consisting of electrolysers, storage tanks, and fuel cells can be implemented as well as batteries. The requirements of the hydrogen purification unit is missing from literature. We measured the same for a 4.5 kW PEM electrolyser to be 0.8 kW for 10 min. A simulation to hybridize the hydrogen system, including its purification unit, with lithium-ion batteries for energy storage is presented; the batteries also support the electrolyser. We simulated a scenario for operating a Dutch household off-electric-grid using solar and wind electricity to find the capacities and costs of the components of the system. Although the energy use of the purification unit is small, it influences the operation of the system, affecting the sizing of the components. The battery as a fast response efficient secondary storage system increases the ability of the electrolyser to start up.
Microcontact printing: limitations and achievementsMicrocontact printing (µCP) offers a simple and low-cost surface patterning methodology with high versatility and sub-micrometer accuracy.This technology has undergone a spectacular evolution since its invention, improving its capability to form sub-100 nm SAM patterns of various polar and apolar materials and biomolecules over macroscopic areas.Several developments of µCP are discussed in this work detailing various printing strategies.New printing schemes with improved stamp materials render µCP a reproducible surface patterning technique with high pattern resolution.New stamp materials and PDMS surface treatment methods allow the use of polar molecules as inks.Flat elastomeric surfaces and low-diffusive inks push the feature sizes to the nanometer range.Chemical and supramolecular interactions between the ink and the substrate increase the applicability of the µCP process.
A fundamental and systematic study on the fabrication of a supramolecularly assembled nanostructure of an organic ligand-capped CdS nanocrystal (NC) and multiple heptamine β-cyclodextrin ((NH(2))(7)βCD) molecules in aqueous solution has been here reported. The functionalization process of presynthesized hydrophobic CdS NCs by means of (NH(2))(7)βCD has been extensively investigated by using different spectroscopic and structural techniques, as a function of different experimental parameters, such as the composition and the concentration of CD, the concentration of CdS NCs, the nature of the NC surface capping ligand (oleic acid and octylamine), and the organic solvent. The formation of a complex based on the direct coordination of the (NH(2))(7)βCD amine groups at the NC surface has been demonstrated and found responsible for the CdS NC phase transfer process. The amine functional group in (NH(2))(7)βCD and the appropriate combination of pristine capping agent coordinating the NC surface and a suitable solvent have been found decisive for the success of the CdS NC phase transfer process. Furthermore, a layer-by-layer assembly experiment has indicated that the obtained (NH(2))(7)βCD functionalized CdS NCs are still able to perform the host-guest chemistry. Thus, they offer a model of a nanoparticle-based material with molecular receptors, useful for bio applications.
