ABSTRACTTo investigate the mechanism of the nitro-alkanes initiation effect on the pyrolysis of hydrocarbons, pyrolysis experiments were conducted on n-C10H22, C2H5NO2, and a binary mixture of both compounds using synchronous vacuum ultraviolet photoionization mass spectrometry. These experiments were performed within a heated flow tube under varying pressure conditions of 30 and 760 Torr. Identifying and measuring pyrolysis species, comprising stable species and radicals, provides insights into the mechanism underlying the pyrolysis and the interaction of n-C10H22 and C2H5NO2. The findings demonstrate that C2H5NO2 can reduce the initial decomposition temperature of n-C10H22, and the acceleration effect on pyrolysis becomes more pronounced with an increase in experimental pressure. The addition of C2H5NO2 also affects the distribution of alkanes, alkenes, dienes, and alkynes. A detailed elementary reaction-dynamics model comprising 223 species and 1730 reactions was established and used to simulate the distribution of C2H5NO2, n-C10H22, major species, and significant intermediates observed in the experiments. The results prove that the developed model exhibits good accuracy in predicting experimental results and enables a detailed analysis of the initiation mechanism of C2H5NO2 on n-C10H22. The impact of C2H5NO2 on the conversion rate and selectivity of pyrolysis products of n-C10H22 is highlighted and elucidated.KEYWORDS: Initiated pyrolysisnitroethanekinetic mechanism Disclosure statementNo potential conflict of interest was reported by the author(s).Supplementary materialSupplemental data for this article can be accessed online at https://doi.org/10.1080/00102202.2023.2284270Additional informationFundingThe work was supported by the National Natural Science Foundation of China [52106137].
'/%3e%3cuse xlink:href='%23a' transform='rotate(23.036 .093 25.536)'/%3e%3cuse xlink:href='%23a' transform='rotate(45.87 1.273 16.18)'/%3e%3cuse xlink:href='%23a' transform='rotate(69.945 .996 12.078)'/%3e%3cuse xlink:href='%23a' transform='rotate(20.66 -19.689 31.932)'/%3e%3c/svg%3e)
'/%3e%3cuse xlink:href='%23a' transform='translate(288.889 -214.211)'/%3e%3cuse xlink:href='%23a' transform='translate(108 342.749)'/%3e%3cuse xlink:href='%23a' transform='translate(469.189 342.749)'/%3e%3c/svg%3e)