In situ high-temperature Raman spectra of polycrystalline KBi(MoO4)2 were recorded from room temperature to 1073 K. Thermal stability of the monoclinic KBi(MoO4)2 was examined by temperature-dependent XRD. The monoclinic phase transformed into the scheelite tetragonal structure at 833 K, and then to the monoclinic phase at 773 K. Quantum chemistry ab initio calculation was performed to simulate the Raman spectra of the structure of KBi(MoO4)2 high-temperature melt. The experimental Raman band at 1023 K was deconvoluted into seven Gaussian peaks, and the calculated results were in good agreement with the experimental data. Therefore, the vibrational modes of Raman peaks of molten KBi(MoO4)2 were assigned. It was confirmed that the isolated structure of [Bi(MoO4)2]- monomer, consisting of Mo6+ centers and Bi3+ sub-centers connected by edge-sharing, mainly exists in the melt of KBi(MoO4)2.
A Flash-ADC data acquisition (DAQ) system has been developed for the drift chamber array designed for the External-Target-Experiment at the Cooling Storage Ring at the Heavy Ion Research Facility, Lanzhou. The simplified readout electronics system has been developed using the Flash-ADC modules and the whole waveform in the sampling window is obtained, with which the time and energy information can be deduced with an offline processing. A digital filter algorithm has been developed to discriminate the noise and the useful signal. With the digital filtering process, the signal to noise ratio (SNR) is increased and a better time and energy resolution can be obtained.
The mineralogy and microstructure of sinter play an important role in determining the physical and metallurgical properties of iron ore sinter. Characterisation of sinter phases is, therefore, a cost-effective and complementary tool to conventional physical and metallurgical testing of iron ore sinter in evaluating and predicting sinter quality. Over the years, CSIRO (Commonwealth Scientific and Industrial Research Organisation) has developed a scheme for characterising iron ore sinter which classifies primary sinter phases, such as un-reacted and partially reacted haematite, magnetite and remnant fluxes, and secondary phases including silico-ferrite of calcium and aluminium (SFCA), secondary haematite and magnetite, glass and larnite. Quantification of these phases has traditionally been carried out by manual point counting under a petrographic microscope. However, new technologies based on automated optical image analysis, quantitative X-ray diffraction and scanning electron microscopy are now available for evaluation. In this study, two sinter samples of varying chemistry were prepared and characterised using both point counting and automated optical image analysis. Quantification of sinter phases is a complementary tool for comparing the physical properties of sinter obtained from various sinter blends, and sinter phase quantification results can be used for comparing pot-grate sinter with different metallurgical properties.
A construction site is an open and dynamic space. Construction accidents have been the top-ranked occupational accidents among all industries around the world. Due to the limited quality and quantity of occupational safety supervisors on construction sites, it is difficult to control or prevent risks in real-time. Therefore, a real-time safety warning system based on a deep learning technique (DL) is developed for lifting operations in building construction, called a portable lightweight lifting safety control station (PLSCS). Two modes can be switched manually by the supervisor. If the mode is switched to lifting control mode, PLSCS helps to ensure that nobody is in the hazardous area during lifting operations. The advantages and features of this system are as follows: (1) it warns of the potential safety hazards automatically during the operations; (2) it reduces the workload of occupational safety supervisors; (3) the system is self-powered and easy to carry and deploy. The system was tested and verified in the actual construction site. The results show that the system is useful for improving the safety of lifting operations.
Background and aims This paper aimed to evaluate the use of nonpharmacological interventions for the management of autism spectrum disorder (ASD). The effects of acupuncture and behavioural therapy, two nonpharmalogical interventions, on social function in ASD patients are still controversial. This meta-analysis investigated the impact of these two treatments and compared their effects. Methods Seven electronic databases were systematically searched to identify randomized controlled trials (RCTs) on the use of acupuncture or behavioural therapy for ASD. A meta-analysis was carried out using Review Manager 5.4 software. Continuous data are reported as mean differences (MDs) or standardized mean differences (SMDs) with 95% confidence intervals (CIs). An assessment of methodological quality using the Cochrane risk-of-bias (ROB) tool for trials was carried out. The Grading of Recommendation Assessment, Development, and Evaluation (GRADE) was applied to evaluate the quality (certainty) of evidence for results regarding social function indicators. Results Thirty RCTs on acupuncture and 36 on behavioural therapy were included. Compared with the control condition, body acupuncture (SMD: 0.76, 95% CI: [0.52, 1.01]; low certainty), modern acupuncture technology (SMD: 0.84, 95% CI: [0.32, 1.35]; low certainty), cognitive behavioural therapy (SMD: 0.42, 95% CI: [0.26, 0.58]; high certainty), the Denver model (SMD: 0.61, 95% CI: [0.23, 0.99]; moderate certainty) and social skills training (SMD: 0.56, 95% CI: [0.41, 0.71]; moderate certainty) improved social functioning. Conclusion Behavioural therapies (such as CBT, the Denver model, social skills training), improved the social functioning of patients with ASD in the short and long term, as supported by high- and moderate-quality evidence. Acupuncture (including scalp acupuncture, body acupuncture and use of modern acupuncture technology) also improved social functioning, as supported by low- and very low-quality evidence. More high-quality evidence is needed to confirm the effect of acupoint catgut embedding and Early Intensive Behavioural Intervention (EIBI).