High-performance MoS2 nanopillar arrays characterized with electron injection and light extraction were facilely developed and applied in flexible inverted OLEDs.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
Bromo-functionalized B1-polycyclic aromatic hydrocarbons (PAHs) with LUMOs of less than -3.0 eV were synthesized and used in cross-couplings to form donor-acceptor materials. These materials spanned a range of S1 energies, with a number showing thermally activated delayed fluorescence and significant emission in the near-infrared region of the spectrum. These B1-PAHs represent a useful family of acceptors that can be readily synthesized and functionalized.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
A new ambipolar 3,3′-dimethyl-9,9′-bianthracene derivative (MBAn-(4)-tBu) was designed as a deep blue fluorophore and blue host material for high-performance OLEDs.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
We present a p- and n-doped nonacene compound, NOBNacene, that represents a rare example of a linearly extended ladder-type multiresonant thermally activated delayed fluorescence (MR-TADF) emitter. This compound shows efficient narrow deep blue emission (PL = 410 nm, FWHM = 38 nm, ФPL = 71%, d = 1.18 ms) in 1.5 wt% TSPO1 thin film. The organic light-emitting diode (OLED) using this compound as the emitter shows a comparable electrolumines-cence spectrum (EL = 409 nm, FWHM = 37 nm) and a maximum external quantum efficiency (EQEmax) of 8.5% at CIE coordinates of (0.173, 0.055). The EQEmax values were increased to 11.2% at 3 wt% doping of the emitter within the emissive layer of the device. At this concentra-tion, the electroluminescence spectrum broadened slightly, leading to CIE coordinates of (0.176, 0.068).
Abstract A series of unsymmetrical arene‐1,3‐squaraine (USQ) derivatives with two, three, or four hydroxy (−OH) substituents, namely, USQ‐2‐OH , USQ‐3‐OH , or USQ‐4‐OH , respectively, were designed and synthesized, and the effect of the number of hydroxy groups on the optoelectronic properties of USQs were investigated. Despite the three compounds having similar UV/Vis absorption and HOMO energy levels, solution‐processed bulk‐heterojunction (BHJ) small‐molecule organic solar cells with USQ‐3‐OH as electron‐donor materials exhibit the highest power conversion efficiency of 6.07 %, which could be mainly attributed to the higher hole mobility and smaller phase separation. It is also noteworthy that the short‐circuit current ( J sc ) of the USQ‐3‐OH ‐based device is as high as 14.95 mA cm −2 , which is the highest J sc values reported for squaraine‐based BHJ solar cells to date. The results also indicate that more −OH substituents on squaraine dyes do not necessarily lead to better photovoltaic performance.
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