An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
A symmetrical rhodamine-triazine derivative was synthesized through step-by-step substitution of rhodamine B ethylenediamine with two chlorines on cyanuric chloride. It showed an extreme selectivity for Al3+ and Cr3+ over other common metal ions and strong fluorescence emission and UV-Visible absorption in the ethanol solution of pH 4. Due to the difference in complexing ability, the recognition of the derivative for Al3+ and Cr3+ was not interfered by other coexisting ions. Under certain conditions, the derivative can be used as high selectivity and high sensitivity Al3+ or Cr3+ fluorescence and colorimetric enhanced probe.
We have strategically incorporated three different fluorophores at tren to construct a multi-energy donor/acceptor "smart" probe L. This probe operates by using three-dimensional scales (response time, wavelength and fluorescence intensity) which allows for the selective recognition and discrimination of the Cu2+, Hg2+, Fe3+ and F- ions.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
Carbon structures are important for converting coal into chemical products and carbon materials. Solid-state 13C nuclear magnetic resonance (NMR) spectroscopy is a powerful approach for determining the structural characteristics of carbon in coal. However, there is much controversy regarding the quantitative reliability of typical cross-polarization magic angle spinning (CP/MAS) 13C NMR experiments of coal. This study systematically investigated the effect of one of the important factors, CP contact time, using six different coal types with Vdaf values ranging from 6% to 44%. A series of experimental results at variable contact times from 0.01 to 10 ms indicated that aromatic and aliphatic carbons undergo polarization transfer at different rates, and the nonprotonated carbon of aromatic groups polarized 2–3 times more slowly than that of aliphatic groups. It is challenging for a single CP/MAS 13C NMR experiment with coal to ensure that each type of carbon is sufficiently polarized before the signal decay of the proton spin–lattice relaxation. As a potential quantitative indicator, the initial magnetization intensity independent of contact time was obtained using a classical five-parameter model for CP dynamics, and the initial aromaticity was further calculated. A linear correlation between the apparent and initial aromaticity was introduced into a calibration method of model compounds to refine the effect of contact time. The modified carbon structural parameters of the coal samples showed better agreement in terms of the H/C atomic ratio, Fourier transform infrared spectroscopy, and empirical aromaticity formulas. These results will help to provide a convenient reference for the quantitative analysis of the carbon structure in coal.