Developing an efficient and durable oxygen reduction electrocatalyst is critical for clean-energy technology, such as fuel cells and metal–air batteries. In this study, we developed a facile strategy for the preparation of flexible, porous, and well-dispersed metal–heteroatom-doped carbon nanofibers by direct carbonization of electrospun Zn/Co-ZIFs/PAN nanofibers (Zn/Co-ZIFs/PAN). The obtained Zn/Co and N co-doped porous carbon nanofibers carbonized at 800 °C (Zn/Co–N@PCNFs-800) presented a good flexibility, a continuous porous structure, and a superior oxygen reduction reaction (ORR) catalytic activity to that of commercial 20 wt% Pt/C, in terms of its onset potential (0.98 V vs. RHE), half-wave potential (0.89 V vs. RHE), and limiting current density (− 5.26 mA cm−2). In addition, we tested the suitability and durability of Zn/Co–N@PCNFs-800 as the oxygen cathode for a rechargeable Zn–air battery. The prepared Zn–air batteries exhibited a higher power density (83.5 mW cm−2), a higher specific capacity (640.3 mAh g−1), an excellent reversibility, and a better cycling life than the commercial 20 wt% Pt/C + RuO2 catalysts. This design strategy of flexible porous non-precious metal-doped ORR electrocatalysts obtained from electrospun ZIFs/polymer nanofibers could be extended to fabricate other novel, stable, and easy-to-use multi-functional electrocatalysts for clean-energy technology.
A novel episulfide-thiol optical polymer with a high refractive index (n = 1.707) can be thermally nanoimprinted at 160 °C with nanoscale size resolution showing excellent pattern fidelity and low defectivity, which exhibit the material as a potential candidate for applications in optical and optoelectronic devices.
The inherent complexity of cellulose, hemicellulose, and lignin contributes to the recalcitrance of lignocellulosic biomass, resulting in a low conversion efficiency and high cost of bioethanol conversion. Pretreatment methods that disrupt the plant cell structure of lignocellulose, such as straw, can significantly enhance the conversion efficiency. In this study, we utilized an acid-assisted mechanocatalytic depolymerization technique to pretreat rice straw, and the results demonstrated a significant disruption of the cellulose structure of the straw. Compared to the untreated straw, the particle size of pretreated straw reduced from 279 μm to 11.8 μm, the crystallinity of cellulose decreased from 43.05% to 22.71%, the specific surface area increased by 177%, and the surface oxygen-to-carbon ratio (O/C) ratio was enhanced by 75%. The changes in microstructure enabled the pretreated straw to achieve a total sugar yield of over 95% within 12 h of enzymatic hydrolysis, significantly superior to the 36.24% yield from untreated straw, the 45.20% yield from acid impregnated straw, and the 73.25% yield from ball milled straw. Consequently, acid-assisted mechanocatalytic depolymerization emerges as a highly effective pretreatment strategy to enhance both the enzymatic hydrolysis and the overall conversion efficiency of rice straw.
It is urgent to pursue appropriate gate photoactive materials for gate-to-channel signal modulation to achieve superior transconductance performances of organic photoelectrochemical transistor (OPECT) sensors. Notably, a hole transfer layer (HTL) participant CdZnS/sulfur-doped Ti3C2 MXene (S-MXene) gate was designed and developed in this work, which exhibited a remarkable signal modulation performance by up to 3 orders of magnitude. Because of the incorporation of S-MXene with an enhanced electrical conductivity as the effective HTL, the signal modulation capabilities of the CdZnS/S-MXene photoactive gate were superior to those of CdZnS and CdZnS/MXene. This incorporation inhibited the recombination of the interfacial charge and facilitated the transfer of photogenerated holes, thus enhancing the photoelectric conversion performance. This enhancement facilitated fast electron transfer with a larger effective photovoltage to augment the dedoping ability of channel ions. Based on these findings, an aptasensing platform that exhibited good performance was constructed using the proposed OPECT device, with ofloxacin as a model target and an aptamer for specific recognition. The developed OPECT aptasensor had various advantages, including a high sensitivity, good linear range (1.0 × 10–13 to 1.0 × 10–6 M), and low limit of detection (3.3 × 10–15 M). This study provided a proof-of-concept for the generalized development of HTL participant gates for OPECT sensors and other related applications.
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