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    Advanced Rectifier Technologies for Electrolysis-Based Hydrogen Production: A Comparative Study and Real-World Applications
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    Abstract:
    In response to the growing significance of hydrogen as a clean energy carrier, this study investigates the advanced rectifier technologies employed in electrolytic hydrogen production. First, the topologies of three rectifiers typically employed in industry—24-pulse thyristor rectifiers, insulated gate bipolar transistor (IGBT) rectifiers, and 24-pulse diode rectifiers with multi-phase choppers—are described in detail. Subsequently, at a constant 5 MW power level, the three rectifiers are compared in terms of rectifier efficiency, grid-side power quality, power factor, and overall investment cost. The results indicate that in comparison to the other two rectifiers, the thyristor rectifier provides superior efficiency and cost advantages, thereby maintaining a dominant market share. Additionally, case studies of rectifier power supplies from three real-world industrial projects are presented, along with actual grid-side power quality data. Finally, the challenges, potential applications, and future prospects of rectifiers in renewable energy-based hydrogen production are discussed and summarized.
    Keywords:
    Rectifier (neural networks)
    The steam electrolysis performance of a Ni-based electrode-supported tubular cell with a Sc2O3-stabilized ZrO2 electrolyte was evaluated at 650°C for various concentrations of H2 and O2 in the supply gases. It was found that an increase in the concentration of electrolytic products (H2 and O2) around the relevant electrode decreased the electrode polarization, and enhanced the electrolysis performance. This result suggests that the electrolysis can be performed with no carrier gases, and the direct storage of the steam electrolysis products H2 and O2 is feasible.
    High Temperature Electrolysis
    Electrolytic cell
    High-pressure electrolysis
    Electrolysis of water
    Power-to-Gas
    Citations (2)
    Solid oxide fuel cells produced at Risø National Laboratory have been tested as electrolysis cells by applying an external voltage. Results on initial performance and durability of such reversible solid oxide cells at temperatures from 750 to and current densities from are reported. The full cells have an initial area specific resistance as low as for electrolysis operation at . During galvanostatic long-term electrolysis tests, the cells were observed to passivate mainly during the first of electrolysis. Cells that have been passivated during electrolysis tests can be partly activated again by operation in fuel cell mode or even at constant electrolysis conditions after several hundred hours of testing.
    High Temperature Electrolysis
    Electrolytic cell
    Passivation
    Citations (225)
    Electrolysis of aqueous glycerin using polymer electrolyte membrane (PEM) was investigated. Electrolysis of aqueous glycerin was achieved with lower applied cell voltage (0.4 V) than that of water and simultaneously hydrogen was produced from the cathode side. Electrolysis efficiency of aqueous glycerin was increased with an increase in operating temperature.
    Electrolysis of water
    Electrolytic cell
    High Temperature Electrolysis
    Citations (2)