Effect of Hydrogenation on the Magnetic and Magnetocaloric Properties of Rare Earth Intermetallic Compounds Tb0.33Ho0.33Er0.33Ni and Dy0.33Ho0.33Er0.33Ni
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The magnetocaloric effect describes the change in temperature of a magnetic material under adiabatic conditions through the application or removal of an external magnetic field. This effect is particularly pronounced at temperatures and fields corresponding to magnetic phase transitions, and it is a powerful and widely used tool for investigating t
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The principles of magnetic cooling and the magnetocaloric properties of various magnetic compounds have been presented with a special focus on materials with giant and colossal magnetocaloric parameters. The magnetocaloric properties of manganites and cobaltites have been considered. The maximum entropy change in polycrystalline La0.7Ca0.3MnO3 for the field of 2 T reaches 8 J·kg –1 ·K –1 , exceeding that of gadolinium. It is suggested that the manganites with superior magnetocaloric properties and low material costs are attractive magnetic refrigerator materials for technical applications.
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Magnetic refrigeration
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Recently, there has been a focus on the need for efficient refrigeration technology without the use of expensive or harmful working fluids, especially at temperatures below 30 K. Solid state refrigeration, based on the magnetocaloric effect, provides a possible solution to this problem. The rare-earth chromites (RCrO3), especially DyCrO3, with its large magnetic moment dysprosium ion, are potential candidates for such an application. The Dy3+ ordering transition at low temperatures (<10 K) likely causes a large magnetocaloric response in this material. This study investigates the possibility of tuning the magnetocaloric properties through the use of rare-earth substitution. Both Y3+ and Ho3+ substitutions were found to decrease the magnetocaloric response by disrupting the R3+ ordering. Whereas Er3+ substitution was found to increase the magnetocaloric response, likely due to an increase in the R3+ ordering temperature. The large magnetocaloric entropy change of Er3+ substituted DyCrO3 (10.92 J/kg K with a relative cooling power of 237 J/kg at 40 kOe and 5 K) indicates that this material system is well suited for low temperature (<30 K) solid state refrigeration applications.
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In this work we investigate magnetocaloric effect and heat capacity of Gd cold rolled ribbons. Such materials are easy to produce, they are flexible and convenient for using in magnetic cooling devices. It is shown that the magnetocaloric effect is strongly dependent on thickness of the ribbons. Severely rolled ribbons demonstrate rather a small magnetocaloric effect. However, a special heat treatment procedure makes it possible to enhance the effect up to the value observed in polycrystalline Gd.
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Magnetic refrigeration
Curie
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In this work we report the results of investigation of the magnetocaloric effect in Gd 100- x Y x ( x = 0, 5, 10, 15) cold rolled ribbons. It is shown that the magnetocaloric effect exists within a wide temperature interval 258-295 K and it is comparable with the magnetocaloric effect observed in bulk samples of pure gadolinium. The value of the magnetocaloric effect in the rolled samples is reduced in comparison with the bulk samples and strongly depends on a degree of plastic deformation. High temperature heat treatment can restore a value of the magnetocaloric effect in the cold rolled ribbons up to initial ones. Thus, cold rolling is proposed to be a promising technique for producing thin forms of magnetocaloric materials for heat exchangers of magnetic cooling devices.
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