13C, 25Mg, and 43Ca Solid-State NMR for the Purpose of Dolomitic Marbles Provenance Elucidation
Isabelle PianetAnna Gutiérrez García-MorenoMarie-Claire SavinNicolas FrèrebeauJulien TréboscPierre FlorianMaría Pilar Lapuente Mercadal
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Abstract:
The study of the provenance of dolomitic marble artefacts has become relevant since it was discovered that quarries of this marble other than that of Cape-Vathy located on the island of Thasos have been exploited since Antiquity. To improve our knowledge about the provenance of materials and the extent of their dispersion, multiple archaeometric studies were performed in the past including isotope analyses, petrography, cathodoluminescence, and elemental analyses. In the present work, solid-state nuclear magnetic resonance (NMR) spectroscopy has been added to this panel of techniques. NMR allows the characterization of the material at a molecular level by looking at different nuclei: carbon, magnesium, and calcium. Statistical analysis of the data collected on both quarry samples and archaeologic items was also implemented and clearly demonstrates the efficiency of a holistic approach for provenance elucidation. Finally, the first 25Mg NMR tests have shown the potential of this technique to discriminate between dolomitic marbles of different provenance. The results are discussed in terms of their historical meaning and illustrate the exploitation of sources of dolomitic marbles other than the Greek Thasos source.Keywords:
Characterization
Most studies of sandstone provenance involve modal analysis of framework grains using techniques that exclude the fine-grained breakdown products of labile mineral grains and rock fragments, usually termed secondary matrix or pseudomatrix. However, the data presented here demonstrate that, when the proportion of pseudomatrix in a sandstone exceeds 10%, standard petrographic analysis can lead to incorrect provenance interpretation. Petrographic schemes for provenance analysis such as QFL and QFR should not therefore be applied to sandstones containing more than 10% secondary matrix. Pseudomatrix is commonly abundant in sandstones, and this is therefore a problem for provenance analysis. The difficulty can be alleviated by the use of whole-rock chemistry in addition to petrographic analysis. Combination of chemical and point-count data permits the construction of normative compositions that approximate original framework grain compositions. Provenance analysis is also complicated in many cases by fundamental compositional alteration during weathering and transport. Many sandstones, particularly shallow marine deposits, have undergone vigorous reworking, which may destroy unstable mineral grains and rock fragments. In such cases it may not be possible to retrieve provenance information by either petrographic or chemical means. Because of this, pseudomatrix-rich sandstones should be routinely included in chemical-petrological provenance analysis. Because of the many factors, both pre- and post-depositional, that operate to increase the compositional maturity of sandstones, petrologic studies must include a complete inventory of matrix proportions, grain size and sorting parameters, and an assessment of depositional setting.
Matrix (chemical analysis)
Lithic fragment
Arenite
Siliciclastic
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Phyllite
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A recent project to investigate the stone artefacts preserved in the Egyptian Antiquity Museum of Turin has been undertaken, with the aim of supplying their systematic classification and suggesting the provenance site of the original raw materials. This paper focuses on seven sculptures dating back to the New Kingdom (18th–19th Dynasties): the statue of Ramses II, three of the 21 sculptures of the goddess Sekhmet, the statue of the goddess Hathor, the Ram‐headed Sphinx and the sarcophagus lid of Nefertari. Petrographic observations have shown that all the sculptures are made of granitoid rocks, with variable composition from granite to granodiorite and tonalite. The observation of strong macroscopic analogies with the so‐called black and red granites outcropping in the Aswan area has suggested a common origin of all the raw materials used for their manufacture. In order to verify this provenance hypothesis, several samples were collected in the Aswan quarry districts. According to results of a minero‐petrographic and geochemical comparison between the statues and the Aswan quarry samples, it was possible to identify the source area of the stone sculptures and finally to highlight the importance of an archaeometric approach to the solution of archaeological problems.
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Abstract Fragments of marble revetment and floor slabs as well as some broken statuary and vessels were recovered from the excavation of a Roman temple in the harbor town of Berenike on the Red Sea coast of Egypt. Petrographic analyses, including optical, cathodoluminescence, and scanning electron microscopy as well as isotopic analyses (δ 13 C, δ 18 O, 87 Sr/ 86 Sr), were conducted to determine the provenance of the marble. The aim was to reconstruct the commercial ties that led to this prized building stone being brought to Berenike. Most, if not all, of the slabs are of banded gray to white marble showing properties indicative of a Prokonnesian origin. This marble, exploited on Marmara Island (Sea of Marmara, Turkey) and extensively utilized throughout the Mediterranean, including Egypt from at least the second century A.D., might have been procured from the marble depots in Alexandria. This could have involved engaging a team of Bithynian master craftsmen for the project, presumably to embellish the main temple of the city during the reign of the Roman emperor Hadrian. The statuary and vessel finds are composed of white marble representing several sources. Some coarse‐grained specimens were surely extracted in Prokonnesos. For others, the source is uncertain and the likely candidates are Prokonnesos, Paros (Cyclades, Aegean Sea), and Ephesos (Aegean coast of Asia Minor). The fine‐grained varieties represented high‐quality Dokimian (Afyon region, Asia Minor) and most likely expensive Parian ( lychnites type) marble. Marble from the ancient Gebel Rokham quarries in Egypt was also examined for comparison, but its properties have excluded this source in the case of the marble artifacts from Berenike analyzed in this work.
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