Bifunctional BiPd Alloy Particles Anchored on Carbon Matrix for Reversible Zn–CO2 Battery
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Exploring reversible Zn–CO2 batteries holds great promising potential for future CO2 fixation and energy supply. Herein, the bifunctional PdBi alloy anchoring on carbon substrate (BiPdC) is proposed for simultaneously catalyzing carbon dioxide reduction reaction (CO2RR) and formic acid oxidation (FAO). The synergistic effect between Pd and Bi overcomes the sluggish kinetics of CO2RR and FAO, causing the HCOOH Faraday efficiency (FEHCOOH) of 63.4% and 6.2 mA cm–2 current density for FAO. Benefiting from the CO2–HCOOH interconversion, the homemade reversible Zn–CO2 battery exhibits the optimal 52.6% FEHCOOH and 1.1 V voltage gap within 45 h of cycling.Keywords:
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1. Photosynthetic carbon dioxide fixation 2. Partial reactions and chemical rescue of site-directed mutants 3. Rubisco as mechanistic probes 4. Elements of the structure of ribulose 5. Learning from Rubisco's mistakes 6. Tests and models of mechanisms for biotin-dependent carbon dioxide fixation 7. Chemistry of B12 derivations related to their roles in bacterial carbon dioxide fixation 8. Stoichiometric and catalytic activation of carbon dioxide on transition- metal complexes 9. Organometallic chemistry of carbon dioxide pertinent to catalysis 10. Catalytic additions of carbon dioxide adducts to alkynes 11. Activation and reduction of carbon dioxide to formylmethanofuran 12. Hydrogenatian of carbon dioxide by catalysts 13. Carbon dioxide as an organic building block 14. Electrochemical syntheses involving carbon dioxide 15. Photochemical electron transfer applied to the reduction of carbon dioxide 16. Room temperature catalytic and photocatalytic fixation of carbon dioxide 17. Retrodiction of carbon dioxide fixation towards a chemoautotropic origin of life 18. Structure - activity correlations in carbamoyl phosphate synthetases 19. How enzymes deal with carbon dioxide and bicarbonate 19. Cyanobacterial carbon dioxide concentrating mechanism 20. Molecular biology and biochemistry of carbon dioxide
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This paper analyzes three tapes of photosynthetic carbon dioxide fixation paths,compares the differences of different carbon dioxide fixation paths in the water utilization,and advances some quick identification methods of C3 and C4 plants.
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This review introduces the recent progresses on the fixation of carbon dioxide (CO2) including 1) the reactions of carbon dioxide with alcohols in the presence of base; 2) the reactions of carbon dioxide with amines in the presence of base; and 3) the transition metal catalyzed carbon dioxide insertion reactions. In the section of transition metal catalyzed fixation of carbon dioxide, we mainly focus on the catalytic process of carbon dioxide insertion reactions promoted by metal catalysts and the emphasis is put on the preparation of the corresponding carbonates or carbamates from CO2 and their further transformations. Keywords: Carbon Dioxide, carbonates, carbamates
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With the Kyoto Protocol entering into force,the emission reduction levels of greenhouse gas,especially carbon dioxide,has attracted more and more important attention from governments and enterprises globally.It becomes a hot topic in environmental research fields.The recent progress in carbon dioxide fixation by microalgae is reviewed in this paper.The following research fields,such as screening and breeding of microalgae with high capability of carbon dioxide fixation,the mechanism of carbon dioxide fixation by microalgae,the process development of carbon dioxide fixation by microalgae,and the comprehensive utilization of microalgae after carbon dioxide fixation done,are discussed respectively.
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Abstract The carbon dioxide concentrating mechanism is a variation of photosynthesis in which the algae raise the level of carbon dioxide in the cell many times over the environmental concentration of carbon dioxide. The carbon dioxide concentrating mechanism enhances carbon dioxide fixation and growth in algae.
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Total inorganic carbon
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Correction for ‘Effects of the support on bifunctional one-step synthesis of methylal via methanol oxidation catalysed by Fe–Mo-based bifunctional catalysts’ by Meng Yuan et al. , Sustainable Energy Fuels , 2021, 5 , 246–260, https://doi.org/10.1039/D0SE01194K.
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Abstract The carbon dioxide concentrating mechanism is a variation of photosynthesis in which the algae raise the level of carbon dioxide in the cell many times over the environmental concentration of carbon dioxide. The carbon dioxide concentrating mechanism enhances carbon dioxide fixation and growth in algae.
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Total inorganic carbon
Carbon respiration
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This review introduces the recent propresses in the fixation of carbon dioxide (CO^2) including, (1) the reactions of carbon dioxide with alcohols in the presence of base, (2) the reaction of carbon dioxide with amines in the presence of base, and (3) the transition metal catalyzed carbon dioxide insertion reactions In the section of transition metal catalyzed fixation of carbon dioxide, we mainly focus on the catalytic process of carbon dioxide insertion reactions promoted by metal catalysts, and the emphases are given on the preparation of the corresponding carbonates or carbamates from CO^2 and their further transfomations.
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Carbon dioxide reforming
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Abstract The McIntosh apple in storage was found to produce malic acid by fixation of carbon dioxide at a rate of about half of the net daily acid loss. The contribution of this reaction to the production of amino‐acids and protein was also quantitatively significant. The fixation activity rose to a high level at the time of harvest and continued to be high throughout the storage period. The rate of uptake of carbon dioxide increased with rising concentration of carbon dioxide in the external atmosphere.
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Controlled atmosphere
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