Ruthenium-Catalyzed Direct Oxidative Alkenylation of Arenes through Twofold C–H Bond Functionalization in Water: Synthesis of Ethyl (E)-3-(2-Acetamido-4-methylphenyl)acrylate
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Surface Modification
Ethyl acrylate
Methyl acrylate
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Patch test
Ethyl acrylate
Patch Testing
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Methyl acrylate
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Data on allergic contact dermatitis from acrylates and 4 patients sensitized during routine patch testing are reported. During 1982-1985, we used 7 different acrylates for tests. 1 patient out of 22 (= 4.5%) was sensitized to ethyl acrylate and butyl acrylate (1% pet.). Since September 1985, we have used a commercial (meth)acrylate series containing 28 substances. 3 of 24 patients tested became sensitized to ethyl acrylate, 2-hydroxyethyl acrylate and 2-hydroxypropyl acrylate (0.5% pet.). Because active sensitization with acrylates can be very harmful, it may be necessary to use lower concentrations than recommended. Currently, we test ethyl acrylate, 2-hydroxyethyl acrylate and 2-hydroxypropyl acrylate at 0.167% pet.
Ethyl acrylate
Patch test
Patch Testing
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The AlCl 3 -promoted reactions of 2-methyl- and of 2-phenylfuran with ethyl propiolate afford as major products ethyl 5-hydroxy-2-methyl- and 2-phenylbenzoates (6a, 6b). Also isolated as minor by-products of these reactions are ethyl 3-(2-furyl-5-methyl)acrylate (5a), ethyl 3-(2-furyl-5-phenyl)acrylate (5b), ethyl 3,3-di(2-furyl-5-methyl)propionate (10a), ethyl 3,3-di(2-furyl-5-phenyl)propionate (10b), and ethyl 2-hydroxy-5-methylbenzoate (8a).
Ethyl acrylate
Methyl acrylate
Ethyl ester
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Ethyl acrylate
Methyl acrylate
Butyl acrylate
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With ethyl methacrylate,butyl acrylate,2-hydroxy ethyl methacrylate,methacrylic acid 2,2,2-trifluoroethyl ester as the raw materials,fluoro-acrylate copolymer are prepared by solution polymerization.The hardness,adhesion,waterproofness,solvent resistance and surface performance are determined.The testing result indicates that the films made by fluoro-acrylate copolymer solution have better properties than those made by pure acrylate copolymer.
Ethyl acrylate
Butyl acrylate
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Abstract The aminocyanopentenedioate (I) dimerizes in refluxing pyridine to give the pyridinedione (II) as the major product.
Ethyl acrylate
Ethyl ester
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An acrylate with tridentate ligand was prepared from CO2 and ethylene. The prepared acrylate was reacted with iodomethane to produce methyl acrylate. Effect of the reaction time on the product yield was investigated. The results indicate that controlling reaction time in synthesizing acrylate and prolonging reaction time in synthesizing methyl acrylate can increase the conversion.
Methyl acrylate
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The title compound, C15H15NO4, which is a key intermediate in the synthesis of compounds used in organic light-emitting devices, has been synthesized by the reaction of 5-(chloromethyl)quinolin-8-ol hydrochloride with 2-hydroxyethyl acrylate. Molecules in the solid state are linked by O—H⋯N intermolecular hydrogen bonds to generate centrosymmetric dimers.
Ethyl acrylate
Meth-
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