Platinum Nanoparticles as Potent Anticancer and Antimicrobial Agent: Green Synthesis, Physical Characterization, and In-Vitro Biological Activity
Mohammadhassan Gholami‐ShabaniFattah SotoodehnejadnematalahiMasoomeh Shams‐GhahfarokhiAli EslamifarMehdi Razzaghi‐Abyaneh
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For the first time,the electrooxidation of methanol was investigated on the platinum nanoparticles-modified platinum electrode using cyclic voltammetry(CV) and electrochemical impedance spectroscopy(EIS) techniques.The results demonstrated that the oxidation current of methanol was greatly enhanced due to the immobilization of platinum nanoparticles,and also indicated that the increased oxidation current was not only originated from the enhancement of electrode surface and nanoparticles of platinum had an peculiar catalysis for the methanol oxidation.
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Colloidal silica modified with a hydridosilsesquioxane (HSiO3/2) layer reacted with Karstedt's catalyst, bis(1,3-divinyl,1,1,3,3-tetramethyldisiloxane) platinum(0), to give catalytically active surface-bound platinum nanoparticles with an average diameter of 2 nm. The supported platinum nanoparticles could be recycled through at least three consecutive hydrosilation reactions while maintaining their catalytic activity. It is postulated that the mesh microstructure of the grafted hydridosilsesquioxane layer supports and protects the supported platinum nanoparticles from aggregating into larger inactive platinum species.
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