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    Compositional variations in naturalgoethite and other oxy-hydroxides insupergene ore deposits.
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    Abstract The results of a complex investigation of the sulphate and arsenate assemblages forming in the weathering zone of selected ore deposits in the Sudetes are presented. The development of the weathering zone has been characterised in the polymetallic ore deposits at Miedzianka-Ciechanowice and Radzimowice, and the pyrite deposit at Wieściszowice, which differ in the chemical compositions of the ore and barren minerals and the hydrological conditions. Secondary sulphate and arsenate mineral assemblages vary significantly among the ore deposits under study. Their crystallization is discussed, taking into consideration the stability of particular minerals and the paths of their transformation. It is shown that these minerals have great potential as indicators of weathering processes. A significant role for microorganisms in the formation of the weathering zone of the ore deposits under study is also proven.
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    Cobalt is an important strategic metal of major industrial countries. In order to invoke the importance of the cobalt deposits to the strategic industries in China, this paper aims to introduce the different types of the cobalt deposits in the worldwide, to review the ore mechanism of the cobalt deposits and to propose the research directions of the future studies for the cobalt deposits. Global cobalt resources can be grouped into two deposit types: terrestrial and seafloor deposits. The major terrestrial cobalt deposits include sediment-hosted stratiform copper-cobalt, nickel-cobalt laterite, and magmatic sulfide copper-nickel deposits. Other sources include black shales hosted, skarn and replacement, metasedimentary rocks hosted, iron oxide copper-gold deposits, volcanic massive sulfides, polymetallic veins (five-element veins and other vein types), and Mississippi Valley-Type lead-zinc deposits. Seafloor cobalt-related deposits are mainly iron-manganese-cobalt nodules and crusts, which are hardly explored and productive. The detailed information of the major cobalt deposits is also listed, presenting the tonnage and grade of various types of the cobalt deposits in China. The polymetallic veins and black shales hosted types have the highest grade, and both types should be paid more attentions during the mineral exploration. For the geochemical behavior of the cobalt during the magmatic and hydrothermal environment, the partition coefficient of cobalt in the process of mantle melting under different tectonic background and water contents are relatively stable. Also, during the fractional crystallization of ultramafic-mafic magmas in the magmatic sulfide deposits, cobalt has a slight preference for olivine relative to basalt. In hydrothermal ore system, aqueous Cobalt(II) chloride complexes play a crucial role in cobalt transport and deposition, and their solubility has a close relationship with the temperature and salinity of the fluids. The debate on the genesis of various cobalt-rich deposits can be considered as the debate on the evaluation between diagenetic and superimposed processes in the ore formation. Besides some polymetallic veins, black-shale hosted, Mississippi Valley-Type lead-zinc, and iron oxide copper-gold deposits, the process of cobalt enrichment has close relationships with the ultramafic-mafic intrusions or volcanic during the magmatic processes, hydrothermal processes, or weathering. Moreover, the multiple-stage hydrothermal processes are also critical to cobalt enrichment. We suggest that the spatial-temporal distribution of different cobalt deposits in China and how their formations are related to the tectonic evolution of the craton and orogenic belt should be investigated immediately to determine the controlling geological factors in different cobalt deposits. Also, the thermodynamic properties of different cobalt-bearing speciation under different physico-chemical environments should be identified. The relationship between geodynamic processes and formation of cobalt-rich deposits needs to be considered. Finally, great attention should be paid to the study of marine iron-manganese-cobalt nodules and crusts and their proper mining technology.

    Cobalt extraction techniques
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    In weakly metamorphosed massive sulfide deposits of the Urals (Dergamysh, Yubileynoe, Yaman-Kasy, Molodezhnoe, Valentorskoe, Aleksandrinskoe, Saf’yanovskoe), banded sulfides (ore diagenites) are recognized as the products of seafloor supergene alteration (halmyrolysis) of fine-clastic sulfide sediments and further diagenesis leading to the formation of authigenic mineralization. The ore diagenites are subdivided into pyrrhotite-, chalcopyrite-, bornite-, sphalerite-, barite- and hematite-rich types. The relative contents of sphalerite-, bornite- and barite-rich facies increases in the progression from ultramafic (=Atlantic) to bimodal mafic (=Uralian) and bimodal felsic (=Baymak and Rudny Altay) types of massive sulfide deposits. The ore diagenites have lost primary features within the ore clasts and dominantly exhibit replacement and neo-formed nodular microtextures. The evolution of the mineralogy is dependent on the original primary composition, sizes and proportions of the hydrothermal ore clasts mixed with lithic serpentinite and hyaloclastic volcanic fragments together with carbonaceous and calcareous fragments. Each type of ore diagenite is characterized by specific rare mineral assemblages: Cu–Co–Ni sulfides are common in pyrrhotite-rich diagenites; tellurides and selenides in chalcopyrite-rich diagenites; minerals of the germanite group and Cu–Ag and Cu–Sn sulfides in bornite-rich diagenites; abundant galena and sulfosalts in barite- and sphalerite-rich diagenites and diverse tellurides characterize hematite-rich diagenites. Native gold in variable amounts is typical of all types of diagenites.
    Bornite
    Covellite
    Felsic
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    Abstract Magnetite and sphalerite in the non-apatitic iron ores and sulphide ores of central Sweden, which are considered to be of volcanogene, syngenetic origin, have been investigated chemically. Microprobe analyses show a pure magnetite, which besides iron, only contains small amounts of additional elements. This concerns also magnetite occurring in iron ore deposits with magnesia-rich alterations, previously attributed to a pyrometasomatic origin, but here considered as para-contemporaneous with the volcanism. The uniform composition of magnetite points to a common source of the iron in the different types of ore. The small contents of manganese (around 1 wt% MnO) in the magnetite of the manganiferous skarn iron ores are due to a higher manganese activity in the ore-bearing solutions. The iron content of sphalerite in the manganiferous skarn iron ores and the sulphide ores varies between 12.8 and 18.6 mole % FeS. The sphalerite in the manganiferous skarn iron ores contains up to 2 wt % Mn. The variations in the iron and manganese contents of the sphalerite are attributed to primary compositional variations during the formation.
    Iron ore
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    Isotopic composition of sulfur was determined in more than 150 samples of sulfides and sulfates from the Levikha ore field. On the basis of the results so obtained, we are discussing the sources of sulfur in the sulfide ores and in sulfates of the ore deposits, physicochemical conditions of their deposition, and their genetic connections with sulfides in the overburden. -- Authors.
    Overburden
    Sulfide Minerals
    Citations (1)
    Synopsis The zoning found in ore deposits is dominantly of two distinctive types: that in syngenetic sedimentary deposits, like the Kupferschiefer, and that in common hydrothermal deposits of either epigenetic or syngenetic characteristics. Here, epigenetic hydrothermal deposits include those commonly classified as vein, porphyry copper, contact metasomatic, and Mississippi Valley deposits; the syngenetic hydrothermal deposits are conformable, massive ores such as at Rammelsberg. The two zoning sequences, beginning nearest the source of the metals, are: in hydrothermal deposits, Fe—Ni—Sn—Cu—Zn—Pb—Ag—Au—Sb—Hg, and in sedimentary deposits, Cu—Ag—Pb—Zn. A zoning sequence represents the natural order of increasing solubilities of the metallic sulphides and other minerals in ore-forming solutions. Comparison of zoning sequences with relative solubilities in proposed ore solutions provides a rigorous test of the efficacy of such solutions. When corrected for relative metal concentrations (mass-action effect), then both theoretically predicted, and experimental relative solubilities of sulphide complexes match precisely the order of hydrothermal zoning. The order in sedimentary zoning is identical to the mass-action-corrected calculation of the sequence in which sulphides must precipitate from solutions containing metallic ions or weak chloride or hydroxyl complexes. The consanguinity of these correlations imply (1) that hydrothermal zoning is the product of deposition from sulphide complexes, and (2) that chloride complexes may be the metal-transporting agent in sedimentary deposits.
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